Extensional ionomeric polymer conductor composite actuators with ionic liquids

Sheng Liu, Minren Lin, Qiming Zhang

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    18 Citations (Scopus)

    Abstract

    Although the Ionic Polymer-Metal Composite (IPMC) actuators developed up to date are in the form of bending actuators, development of extensional actuators based on IMPC is highly desirable from practical applications and fundamental understanding points of view. This talk presents the design, fabrication and characterization of a recent work on an extensional Ionic Polymer-Metal Composite actuator. The extensional actuator consists of the Nafion ionomer as the matrix and the sub-micron size RuO2 particles as the conductive filler for the conductor/ionomr composites. In this investigation, several ionic liquids (IL) were investigated. For a Nafion/RuO2 composite with 1-Ethyl-3-methylimidazolium trifluoromethanesulfonate (EMI-Tf) IL, it was found that as the ions are driven into the ionomer/RuO2 composite (the composite under negative voltage), an extensional strain of 0.9% was observed; while as the ions were expelled from the ionomer/RuO2 composite (under positive voltage), a contraction of-1.2% was observed. The results indicate that multiple ions are participating in charge transport and actuation process. In this paper, we also discuss several design considerations for future extensional actuators with fast response, much improved strain and stress level. Especially an actuator based on multilayer configuration can significantly increase the electric field level in the actuator and consequently significantly improve the actuator speed. The extensional actuator investigated here provides a unique platform to investigate various phenomena related to ion transport and their interaction with the ionomer/conductor matrix to realize high electromechanical performance.

    Original languageEnglish (US)
    Title of host publicationElectroactive Polymer Actuators and Devices (EAPAD) 2008
    DOIs
    StatePublished - Jun 2 2008
    EventElectroactive Polymer Actuators and Devices (EAPAD) 2008 - San Diego, CA, United States
    Duration: Mar 10 2008Mar 13 2008

    Publication series

    NameProceedings of SPIE - The International Society for Optical Engineering
    Volume6927
    ISSN (Print)0277-786X

    Other

    OtherElectroactive Polymer Actuators and Devices (EAPAD) 2008
    CountryUnited States
    CitySan Diego, CA
    Period3/10/083/13/08

    Fingerprint

    Ionic Liquid
    Ionic Liquids
    Conductor
    Ionic liquids
    Actuator
    Polymers
    Actuators
    conductors
    actuators
    Composite
    composite materials
    Composite materials
    polymers
    liquids
    Ionomers
    Ions
    Ionic Polymer-metal Composite
    ions
    Metals
    Voltage

    All Science Journal Classification (ASJC) codes

    • Electronic, Optical and Magnetic Materials
    • Condensed Matter Physics
    • Computer Science Applications
    • Applied Mathematics
    • Electrical and Electronic Engineering

    Cite this

    Liu, S., Lin, M., & Zhang, Q. (2008). Extensional ionomeric polymer conductor composite actuators with ionic liquids. In Electroactive Polymer Actuators and Devices (EAPAD) 2008 [69270H] (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 6927). https://doi.org/10.1117/12.787597
    Liu, Sheng ; Lin, Minren ; Zhang, Qiming. / Extensional ionomeric polymer conductor composite actuators with ionic liquids. Electroactive Polymer Actuators and Devices (EAPAD) 2008. 2008. (Proceedings of SPIE - The International Society for Optical Engineering).
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    abstract = "Although the Ionic Polymer-Metal Composite (IPMC) actuators developed up to date are in the form of bending actuators, development of extensional actuators based on IMPC is highly desirable from practical applications and fundamental understanding points of view. This talk presents the design, fabrication and characterization of a recent work on an extensional Ionic Polymer-Metal Composite actuator. The extensional actuator consists of the Nafion ionomer as the matrix and the sub-micron size RuO2 particles as the conductive filler for the conductor/ionomr composites. In this investigation, several ionic liquids (IL) were investigated. For a Nafion/RuO2 composite with 1-Ethyl-3-methylimidazolium trifluoromethanesulfonate (EMI-Tf) IL, it was found that as the ions are driven into the ionomer/RuO2 composite (the composite under negative voltage), an extensional strain of 0.9{\%} was observed; while as the ions were expelled from the ionomer/RuO2 composite (under positive voltage), a contraction of-1.2{\%} was observed. The results indicate that multiple ions are participating in charge transport and actuation process. In this paper, we also discuss several design considerations for future extensional actuators with fast response, much improved strain and stress level. Especially an actuator based on multilayer configuration can significantly increase the electric field level in the actuator and consequently significantly improve the actuator speed. The extensional actuator investigated here provides a unique platform to investigate various phenomena related to ion transport and their interaction with the ionomer/conductor matrix to realize high electromechanical performance.",
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    Liu, S, Lin, M & Zhang, Q 2008, Extensional ionomeric polymer conductor composite actuators with ionic liquids. in Electroactive Polymer Actuators and Devices (EAPAD) 2008., 69270H, Proceedings of SPIE - The International Society for Optical Engineering, vol. 6927, Electroactive Polymer Actuators and Devices (EAPAD) 2008, San Diego, CA, United States, 3/10/08. https://doi.org/10.1117/12.787597

    Extensional ionomeric polymer conductor composite actuators with ionic liquids. / Liu, Sheng; Lin, Minren; Zhang, Qiming.

    Electroactive Polymer Actuators and Devices (EAPAD) 2008. 2008. 69270H (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 6927).

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

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    N2 - Although the Ionic Polymer-Metal Composite (IPMC) actuators developed up to date are in the form of bending actuators, development of extensional actuators based on IMPC is highly desirable from practical applications and fundamental understanding points of view. This talk presents the design, fabrication and characterization of a recent work on an extensional Ionic Polymer-Metal Composite actuator. The extensional actuator consists of the Nafion ionomer as the matrix and the sub-micron size RuO2 particles as the conductive filler for the conductor/ionomr composites. In this investigation, several ionic liquids (IL) were investigated. For a Nafion/RuO2 composite with 1-Ethyl-3-methylimidazolium trifluoromethanesulfonate (EMI-Tf) IL, it was found that as the ions are driven into the ionomer/RuO2 composite (the composite under negative voltage), an extensional strain of 0.9% was observed; while as the ions were expelled from the ionomer/RuO2 composite (under positive voltage), a contraction of-1.2% was observed. The results indicate that multiple ions are participating in charge transport and actuation process. In this paper, we also discuss several design considerations for future extensional actuators with fast response, much improved strain and stress level. Especially an actuator based on multilayer configuration can significantly increase the electric field level in the actuator and consequently significantly improve the actuator speed. The extensional actuator investigated here provides a unique platform to investigate various phenomena related to ion transport and their interaction with the ionomer/conductor matrix to realize high electromechanical performance.

    AB - Although the Ionic Polymer-Metal Composite (IPMC) actuators developed up to date are in the form of bending actuators, development of extensional actuators based on IMPC is highly desirable from practical applications and fundamental understanding points of view. This talk presents the design, fabrication and characterization of a recent work on an extensional Ionic Polymer-Metal Composite actuator. The extensional actuator consists of the Nafion ionomer as the matrix and the sub-micron size RuO2 particles as the conductive filler for the conductor/ionomr composites. In this investigation, several ionic liquids (IL) were investigated. For a Nafion/RuO2 composite with 1-Ethyl-3-methylimidazolium trifluoromethanesulfonate (EMI-Tf) IL, it was found that as the ions are driven into the ionomer/RuO2 composite (the composite under negative voltage), an extensional strain of 0.9% was observed; while as the ions were expelled from the ionomer/RuO2 composite (under positive voltage), a contraction of-1.2% was observed. The results indicate that multiple ions are participating in charge transport and actuation process. In this paper, we also discuss several design considerations for future extensional actuators with fast response, much improved strain and stress level. Especially an actuator based on multilayer configuration can significantly increase the electric field level in the actuator and consequently significantly improve the actuator speed. The extensional actuator investigated here provides a unique platform to investigate various phenomena related to ion transport and their interaction with the ionomer/conductor matrix to realize high electromechanical performance.

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    Liu S, Lin M, Zhang Q. Extensional ionomeric polymer conductor composite actuators with ionic liquids. In Electroactive Polymer Actuators and Devices (EAPAD) 2008. 2008. 69270H. (Proceedings of SPIE - The International Society for Optical Engineering). https://doi.org/10.1117/12.787597