Fabrication of κ-Carrageenan Fibers by Wet Spinning: Spinning Parameters

Lingyan Kong, Gregory R. Ziegler

Research output: Contribution to journalArticle

9 Scopus citations

Abstract

This study demonstrates the fabrication of κ-carrageenan fibers by a wet-spinning method and discusses three important spinning parameters: coagulation bath composition, spinning rate and post-spinning mechanical drawing. The as-spun fiber diameter decreased with KCl and ethanol concentration in the coagulation bath. In general, the ultimate tensile stress and elongation at break both increased for KCl concentration from 0.1 to 0.5M with and without ethanol, with no significant change above 0.5M. Spinning rate affected the dope flow and thus the polymer orientation (apparent viscosity) and fiber morphology. At spinning rates between 0.25mL/min and 0.33mL/min, the fiber diameter reached a minimum and the fiber surface was smooth. Both an increase and decrease from this spinning rate range increased the fiber diameter and roughness of the fiber surface. Post-spinning drawing of the fiber resulted in even smaller fiber diameter.

Original languageEnglish (US)
Pages (from-to)1805-1817
Number of pages13
JournalMaterials
Volume4
Issue number10
DOIs
StatePublished - Dec 1 2011

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All Science Journal Classification (ASJC) codes

  • Materials Science(all)

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