Ferroelectric Fluoro-Terpolymers with High Dielectric Constant and Large Electromechanical Response at Ambient Temperature

Tze-chiang Chung, A. Petchsuk

Research output: Contribution to journalConference article

Abstract

This paper discusses a new family of ferroelectric polymorphs fluoro-terpolymers comprising vinylidene difluoride (VDF), trifluoroethylene (TrFE), and a chloro-containing third monomer, including vinyl chloride (VC), 1,1-chlorofluoroethylene (CFE), chlorodifluoroethylene (CDFE), chlorotrifluoroethylene (CTFE), with narrow molecular weight and composition distributions. The slightly bulky chlorine atom serves as a kink in the polymer chain, which spontaneously alters the chain conformation and crystalline structure. Comparing with the corresponding VDF/TrFE copolymer, the slowly increasing chlorine content (< 8 mol% of ter-monomer) gradually changes the all-trans chain conformation to tttg+tttg- conformation, without significant reduction of overall crystallinity. Curie (F-P) phase transition temperature between the mixed ferroelectric phases and paraelectric phase (tg+tg- conformation) also gradually reduced to near ambient temperature, with very small activation energy. Consequently, the terpolymers show high dielectric constant (>80) and large electrostrictive response (>5%) at ambient temperature, and exhibiting common ferroelectric relaxor behaviors with a broad dielectric peak that shifted toward higher temperatures as the frequency increased, and a slim polarization hysteresis loop at ambient temperature.

Original languageEnglish (US)
Pages (from-to)41-50
Number of pages10
JournalProceedings of SPIE - The International Society for Optical Engineering
Volume5053
DOIs
StatePublished - Nov 27 2003
EventPROCEEDINGS OF SPIE SPIE - The International Society for Optical Engineering: Smart Structures and Materials 2003 Active Materials: Behavior and Mechanics - San Diego, CA, United States
Duration: Mar 3 2003Mar 6 2003

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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