Ferroelectric relaxor terpolymers: Properties and potential applications

François Bauer, Qiming Zhang, Eric Fousson

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    Ferroelectric materials are intrinsically multifunctional and have found a broad range of applications. A new class of semicrystalline terpolymers comprising vinylidene fluoride (VDF), trifluoroethylene (TrFE), and 1,1-chlor ofluoroethylene (CFE), were prepared at the Institut Franco-Allemand de Recherches in Saint-Louis (ISL) via a suspension polymerization process Relevant studies and results show that this class of electroactive polymers offers unique properties in comparison with other ferroelectric polymers. The terpolymer exhibits high electrostrictive strain (>7%) with relatively high modulus (>0.3GPa). It has been also observed that the large electrostrictive strain is nearly constant in the temperature range from 20°C to 80°C. These terpolymers are strong candidates for new devices. Example of the motion and of the performance of terpolymer in aunimotph configuration is presented._The high room temperature relative dielectric constant (∼ 50), which is the highest among all the known polymers), high induced polarization (∼ 0.05 C/m2), and high electric breakdown field (>400 MV/m) lead to very high volume efficiency for the electric energy storage operate d under high voltage (∼ 10 J/cm3).

    Original languageEnglish (US)
    Title of host publication2006 15th IEEE International Symposium on Applications of Ferroelectrics, ISAF
    DOIs
    StatePublished - Dec 1 2006
    Event2006 15th IEEE International Symposium on Applications of Ferroelectrics, ISAF - Sunset Beach, NC, United States
    Duration: Jul 30 2006Aug 3 2006

    Publication series

    NameIEEE International Symposium on Applications of Ferroelectrics

    Other

    Other2006 15th IEEE International Symposium on Applications of Ferroelectrics, ISAF
    CountryUnited States
    CitySunset Beach, NC
    Period7/30/068/3/06

    Fingerprint

    Terpolymers
    Ferroelectric materials
    Polymers
    Electric energy storage
    Electric breakdown
    Suspensions
    Permittivity
    Polymerization
    Polarization
    Temperature
    Electric potential

    All Science Journal Classification (ASJC) codes

    • Electronic, Optical and Magnetic Materials
    • Electrical and Electronic Engineering

    Cite this

    Bauer, F., Zhang, Q., & Fousson, E. (2006). Ferroelectric relaxor terpolymers: Properties and potential applications. In 2006 15th IEEE International Symposium on Applications of Ferroelectrics, ISAF [4349288] (IEEE International Symposium on Applications of Ferroelectrics). https://doi.org/10.1109/ISAF.2006.4349288
    Bauer, François ; Zhang, Qiming ; Fousson, Eric. / Ferroelectric relaxor terpolymers : Properties and potential applications. 2006 15th IEEE International Symposium on Applications of Ferroelectrics, ISAF. 2006. (IEEE International Symposium on Applications of Ferroelectrics).
    @inproceedings{20a8ae6fc4e246de9f808a5d03484b9e,
    title = "Ferroelectric relaxor terpolymers: Properties and potential applications",
    abstract = "Ferroelectric materials are intrinsically multifunctional and have found a broad range of applications. A new class of semicrystalline terpolymers comprising vinylidene fluoride (VDF), trifluoroethylene (TrFE), and 1,1-chlor ofluoroethylene (CFE), were prepared at the Institut Franco-Allemand de Recherches in Saint-Louis (ISL) via a suspension polymerization process Relevant studies and results show that this class of electroactive polymers offers unique properties in comparison with other ferroelectric polymers. The terpolymer exhibits high electrostrictive strain (>7{\%}) with relatively high modulus (>0.3GPa). It has been also observed that the large electrostrictive strain is nearly constant in the temperature range from 20°C to 80°C. These terpolymers are strong candidates for new devices. Example of the motion and of the performance of terpolymer in aunimotph configuration is presented._The high room temperature relative dielectric constant (∼ 50), which is the highest among all the known polymers), high induced polarization (∼ 0.05 C/m2), and high electric breakdown field (>400 MV/m) lead to very high volume efficiency for the electric energy storage operate d under high voltage (∼ 10 J/cm3).",
    author = "Fran{\cc}ois Bauer and Qiming Zhang and Eric Fousson",
    year = "2006",
    month = "12",
    day = "1",
    doi = "10.1109/ISAF.2006.4349288",
    language = "English (US)",
    isbn = "142441332X",
    series = "IEEE International Symposium on Applications of Ferroelectrics",
    booktitle = "2006 15th IEEE International Symposium on Applications of Ferroelectrics, ISAF",

    }

    Bauer, F, Zhang, Q & Fousson, E 2006, Ferroelectric relaxor terpolymers: Properties and potential applications. in 2006 15th IEEE International Symposium on Applications of Ferroelectrics, ISAF., 4349288, IEEE International Symposium on Applications of Ferroelectrics, 2006 15th IEEE International Symposium on Applications of Ferroelectrics, ISAF, Sunset Beach, NC, United States, 7/30/06. https://doi.org/10.1109/ISAF.2006.4349288

    Ferroelectric relaxor terpolymers : Properties and potential applications. / Bauer, François; Zhang, Qiming; Fousson, Eric.

    2006 15th IEEE International Symposium on Applications of Ferroelectrics, ISAF. 2006. 4349288 (IEEE International Symposium on Applications of Ferroelectrics).

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    TY - GEN

    T1 - Ferroelectric relaxor terpolymers

    T2 - Properties and potential applications

    AU - Bauer, François

    AU - Zhang, Qiming

    AU - Fousson, Eric

    PY - 2006/12/1

    Y1 - 2006/12/1

    N2 - Ferroelectric materials are intrinsically multifunctional and have found a broad range of applications. A new class of semicrystalline terpolymers comprising vinylidene fluoride (VDF), trifluoroethylene (TrFE), and 1,1-chlor ofluoroethylene (CFE), were prepared at the Institut Franco-Allemand de Recherches in Saint-Louis (ISL) via a suspension polymerization process Relevant studies and results show that this class of electroactive polymers offers unique properties in comparison with other ferroelectric polymers. The terpolymer exhibits high electrostrictive strain (>7%) with relatively high modulus (>0.3GPa). It has been also observed that the large electrostrictive strain is nearly constant in the temperature range from 20°C to 80°C. These terpolymers are strong candidates for new devices. Example of the motion and of the performance of terpolymer in aunimotph configuration is presented._The high room temperature relative dielectric constant (∼ 50), which is the highest among all the known polymers), high induced polarization (∼ 0.05 C/m2), and high electric breakdown field (>400 MV/m) lead to very high volume efficiency for the electric energy storage operate d under high voltage (∼ 10 J/cm3).

    AB - Ferroelectric materials are intrinsically multifunctional and have found a broad range of applications. A new class of semicrystalline terpolymers comprising vinylidene fluoride (VDF), trifluoroethylene (TrFE), and 1,1-chlor ofluoroethylene (CFE), were prepared at the Institut Franco-Allemand de Recherches in Saint-Louis (ISL) via a suspension polymerization process Relevant studies and results show that this class of electroactive polymers offers unique properties in comparison with other ferroelectric polymers. The terpolymer exhibits high electrostrictive strain (>7%) with relatively high modulus (>0.3GPa). It has been also observed that the large electrostrictive strain is nearly constant in the temperature range from 20°C to 80°C. These terpolymers are strong candidates for new devices. Example of the motion and of the performance of terpolymer in aunimotph configuration is presented._The high room temperature relative dielectric constant (∼ 50), which is the highest among all the known polymers), high induced polarization (∼ 0.05 C/m2), and high electric breakdown field (>400 MV/m) lead to very high volume efficiency for the electric energy storage operate d under high voltage (∼ 10 J/cm3).

    UR - http://www.scopus.com/inward/record.url?scp=50249140809&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=50249140809&partnerID=8YFLogxK

    U2 - 10.1109/ISAF.2006.4349288

    DO - 10.1109/ISAF.2006.4349288

    M3 - Conference contribution

    AN - SCOPUS:50249140809

    SN - 142441332X

    SN - 9781424413324

    T3 - IEEE International Symposium on Applications of Ferroelectrics

    BT - 2006 15th IEEE International Symposium on Applications of Ferroelectrics, ISAF

    ER -

    Bauer F, Zhang Q, Fousson E. Ferroelectric relaxor terpolymers: Properties and potential applications. In 2006 15th IEEE International Symposium on Applications of Ferroelectrics, ISAF. 2006. 4349288. (IEEE International Symposium on Applications of Ferroelectrics). https://doi.org/10.1109/ISAF.2006.4349288