Ferroelectric Sr3Zr2O7: Competition between Hybrid Improper Ferroelectric and Antiferroelectric Mechanisms

Suguru Yoshida, Koji Fujita, Hirofumi Akamatsu, Olivier Hernandez, Arnab Sen Gupta, Forrest G. Brown, Haricharan Padmanabhan, Alexandra S. Gibbs, Toshihiro Kuge, Ryosuke Tsuji, Shunsuke Murai, James M. Rondinelli, Venkatraman Gopalan, Katsuhisa Tanaka

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

In contrast to polar cation displacements driving oxides into noncentrosymmetric and ferroelectric states, inversion-preserving anion displacements, such as rotations or tilts of oxygen octahedra about cation coordination centers, are exceedingly common. More than one nonpolar rotational mode in layered perovskites can lift inversion symmetry and combine to induce an electric polarization through a hybrid improper ferroelectric (HIF) mechanism. This form of ferroelectricity expands the compositional palette to new ferroelectric oxides because its activity derives from geometric rather than electronic origins. Here, the new Ruddlesden–Popper HIF Sr3Zr2O7, which is the first ternary lead-free zirconate ferroelectric, is reported and room-temperature polarization switching is demonstrated. This compound undergoes a first-order ferroelectric-to-paraelectric transition, involving an unusual change in the “sense” of octahedral rotation while the octahedral tilt remains unchanged. Our experimental and first-principles study shows that the paraelectric polymorph competes with the polar phase and emerges from a trilinear coupling of rotation and tilt modes interacting with an antipolar mode. This form of hybrid improper “antiferroelectricity” is recently predicted theoretically but has remained undetected. This work establishes the importance of understanding anharmonic interactions among lattice degrees of freedom, which is important for the discovery of new ferroelectrics and likely to influence the design of next-generation thermoelectrics.

Original languageEnglish (US)
Article number1801856
JournalAdvanced Functional Materials
Volume28
Issue number30
DOIs
StatePublished - Jul 25 2018

Fingerprint

Ferroelectric materials
antiferroelectricity
inversions
cations
oxides
ferroelectricity
polarization
perovskites
preserving
Oxides
degrees of freedom
Antiferroelectricity
Cations
anions
Positive ions
Polarization
Ferroelectricity
symmetry
room temperature
oxygen

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Yoshida, S., Fujita, K., Akamatsu, H., Hernandez, O., Sen Gupta, A., Brown, F. G., ... Tanaka, K. (2018). Ferroelectric Sr3Zr2O7: Competition between Hybrid Improper Ferroelectric and Antiferroelectric Mechanisms. Advanced Functional Materials, 28(30), [1801856]. https://doi.org/10.1002/adfm.201801856
Yoshida, Suguru ; Fujita, Koji ; Akamatsu, Hirofumi ; Hernandez, Olivier ; Sen Gupta, Arnab ; Brown, Forrest G. ; Padmanabhan, Haricharan ; Gibbs, Alexandra S. ; Kuge, Toshihiro ; Tsuji, Ryosuke ; Murai, Shunsuke ; Rondinelli, James M. ; Gopalan, Venkatraman ; Tanaka, Katsuhisa. / Ferroelectric Sr3Zr2O7 : Competition between Hybrid Improper Ferroelectric and Antiferroelectric Mechanisms. In: Advanced Functional Materials. 2018 ; Vol. 28, No. 30.
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Yoshida, S, Fujita, K, Akamatsu, H, Hernandez, O, Sen Gupta, A, Brown, FG, Padmanabhan, H, Gibbs, AS, Kuge, T, Tsuji, R, Murai, S, Rondinelli, JM, Gopalan, V & Tanaka, K 2018, 'Ferroelectric Sr3Zr2O7: Competition between Hybrid Improper Ferroelectric and Antiferroelectric Mechanisms', Advanced Functional Materials, vol. 28, no. 30, 1801856. https://doi.org/10.1002/adfm.201801856

Ferroelectric Sr3Zr2O7 : Competition between Hybrid Improper Ferroelectric and Antiferroelectric Mechanisms. / Yoshida, Suguru; Fujita, Koji; Akamatsu, Hirofumi; Hernandez, Olivier; Sen Gupta, Arnab; Brown, Forrest G.; Padmanabhan, Haricharan; Gibbs, Alexandra S.; Kuge, Toshihiro; Tsuji, Ryosuke; Murai, Shunsuke; Rondinelli, James M.; Gopalan, Venkatraman; Tanaka, Katsuhisa.

In: Advanced Functional Materials, Vol. 28, No. 30, 1801856, 25.07.2018.

Research output: Contribution to journalArticle

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T2 - Competition between Hybrid Improper Ferroelectric and Antiferroelectric Mechanisms

AU - Yoshida, Suguru

AU - Fujita, Koji

AU - Akamatsu, Hirofumi

AU - Hernandez, Olivier

AU - Sen Gupta, Arnab

AU - Brown, Forrest G.

AU - Padmanabhan, Haricharan

AU - Gibbs, Alexandra S.

AU - Kuge, Toshihiro

AU - Tsuji, Ryosuke

AU - Murai, Shunsuke

AU - Rondinelli, James M.

AU - Gopalan, Venkatraman

AU - Tanaka, Katsuhisa

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N2 - In contrast to polar cation displacements driving oxides into noncentrosymmetric and ferroelectric states, inversion-preserving anion displacements, such as rotations or tilts of oxygen octahedra about cation coordination centers, are exceedingly common. More than one nonpolar rotational mode in layered perovskites can lift inversion symmetry and combine to induce an electric polarization through a hybrid improper ferroelectric (HIF) mechanism. This form of ferroelectricity expands the compositional palette to new ferroelectric oxides because its activity derives from geometric rather than electronic origins. Here, the new Ruddlesden–Popper HIF Sr3Zr2O7, which is the first ternary lead-free zirconate ferroelectric, is reported and room-temperature polarization switching is demonstrated. This compound undergoes a first-order ferroelectric-to-paraelectric transition, involving an unusual change in the “sense” of octahedral rotation while the octahedral tilt remains unchanged. Our experimental and first-principles study shows that the paraelectric polymorph competes with the polar phase and emerges from a trilinear coupling of rotation and tilt modes interacting with an antipolar mode. This form of hybrid improper “antiferroelectricity” is recently predicted theoretically but has remained undetected. This work establishes the importance of understanding anharmonic interactions among lattice degrees of freedom, which is important for the discovery of new ferroelectrics and likely to influence the design of next-generation thermoelectrics.

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