Abstract
A free‐volume theory is developed for the analysis of Fickian diffusion processes in glassy polymers. Equations are presented for the prediction of mutual diffusion coefficients in concentrated glassy polymer‐penetrant systems. The concentration dependence of the mutual diffusion coefficient is dependent on how much free volume the solvent contributes to the system and on how the addition of solvent affects the densification of the polymer matrix. © 1992 John Wiley & Sons, Inc.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1005-1011 |
| Number of pages | 7 |
| Journal | Journal of Polymer Science Part B: Polymer Physics |
| Volume | 30 |
| Issue number | 9 |
| DOIs | |
| State | Published - Jan 1 1992 |
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All Science Journal Classification (ASJC) codes
- Condensed Matter Physics
- Physical and Theoretical Chemistry
- Polymers and Plastics
- Materials Chemistry
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Fickian diffusion in glassy polymer‐solvent systems. / Vrentas, J. S.; Vrentas, Christine Mary.
In: Journal of Polymer Science Part B: Polymer Physics, Vol. 30, No. 9, 01.01.1992, p. 1005-1011.Research output: Contribution to journal › Article
TY - JOUR
T1 - Fickian diffusion in glassy polymer‐solvent systems
AU - Vrentas, J. S.
AU - Vrentas, Christine Mary
PY - 1992/1/1
Y1 - 1992/1/1
N2 - A free‐volume theory is developed for the analysis of Fickian diffusion processes in glassy polymers. Equations are presented for the prediction of mutual diffusion coefficients in concentrated glassy polymer‐penetrant systems. The concentration dependence of the mutual diffusion coefficient is dependent on how much free volume the solvent contributes to the system and on how the addition of solvent affects the densification of the polymer matrix. © 1992 John Wiley & Sons, Inc.
AB - A free‐volume theory is developed for the analysis of Fickian diffusion processes in glassy polymers. Equations are presented for the prediction of mutual diffusion coefficients in concentrated glassy polymer‐penetrant systems. The concentration dependence of the mutual diffusion coefficient is dependent on how much free volume the solvent contributes to the system and on how the addition of solvent affects the densification of the polymer matrix. © 1992 John Wiley & Sons, Inc.
UR - http://www.scopus.com/inward/record.url?scp=0026903153&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0026903153&partnerID=8YFLogxK
U2 - 10.1002/polb.1992.090300908
DO - 10.1002/polb.1992.090300908
M3 - Article
AN - SCOPUS:0026903153
VL - 30
SP - 1005
EP - 1011
JO - Journal of Polymer Science, Part B: Polymer Physics
JF - Journal of Polymer Science, Part B: Polymer Physics
SN - 0887-6266
IS - 9
ER -