Field ionization kinetics: Phenylhexanone

Donald G. Patterson, Richard B. Scott, Peter Brown

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

A Varian Atlas SMIB double focusing mass spectrometer has been modified for field ionization kinetics measurements. Computer programs have been written for the calculation and display of potential maps, ion trajectories, and the transformation to ion lifetimes and phenomenological rate constants. The previously studied cyclohexene system has been used to check the accuracy of our method. The fragment ions generated by phenylhexanone after field ionization have also been examined by field ionization kinetics, including cleavage and rearrangement reactions, H/D randomization and temperature effects.

Original languageEnglish (US)
Pages (from-to)395-401
Number of pages7
JournalOrganic Mass Spectrometry
Volume12
Issue number6
DOIs
StatePublished - Jun 1977

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Molecular Medicine
  • Instrumentation

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    Patterson, D. G., Scott, R. B., & Brown, P. (1977). Field ionization kinetics: Phenylhexanone. Organic Mass Spectrometry, 12(6), 395-401. https://doi.org/10.1002/oms.1210120611