Field ionization kinetics

Phenylhexanone

Donald George Jr Patterson, Richard B. Scott, Peter Brown

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A Varian Atlas SMIB double focusing mass spectrometer has been modified for field ionization kinetics measurements. Computer programs have been written for the calculation and display of potential maps, ion trajectories, and the transformation to ion lifetimes and phenomenological rate constants. The previously studied cyclohexene system has been used to check the accuracy of our method. The fragment ions generated by phenylhexanone after field ionization have also been examined by field ionization kinetics, including cleavage and rearrangement reactions, H/D randomization and temperature effects.

Original languageEnglish (US)
Pages (from-to)395-401
Number of pages7
JournalOrganic Mass Spectrometry
Volume12
Issue number6
DOIs
StatePublished - Jan 1 1977

Fingerprint

Ionization
Ions
ionization
Kinetics
kinetics
ions
Atlases
Mass spectrometers
Random Allocation
Thermal effects
mass spectrometers
temperature effects
Computer program listings
cleavage
Rate constants
Software
Display devices
Trajectories
fragments
trajectories

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Molecular Medicine
  • Instrumentation

Cite this

Patterson, D. G. J., Scott, R. B., & Brown, P. (1977). Field ionization kinetics: Phenylhexanone. Organic Mass Spectrometry, 12(6), 395-401. https://doi.org/10.1002/oms.1210120611
Patterson, Donald George Jr ; Scott, Richard B. ; Brown, Peter. / Field ionization kinetics : Phenylhexanone. In: Organic Mass Spectrometry. 1977 ; Vol. 12, No. 6. pp. 395-401.
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Patterson, DGJ, Scott, RB & Brown, P 1977, 'Field ionization kinetics: Phenylhexanone', Organic Mass Spectrometry, vol. 12, no. 6, pp. 395-401. https://doi.org/10.1002/oms.1210120611

Field ionization kinetics : Phenylhexanone. / Patterson, Donald George Jr; Scott, Richard B.; Brown, Peter.

In: Organic Mass Spectrometry, Vol. 12, No. 6, 01.01.1977, p. 395-401.

Research output: Contribution to journalArticle

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