Formation of saponite by hydrothermal alteration of metal oxides: Implication for the rarity of hydrotalcite

Qi Tao, Qingjin Zeng, Manyou Chen, Hongping He, Sridhar Komarneni

Research output: Contribution to journalArticle

Abstract

Conversion of hydrotalcite (Ht) to saponite was observed by hydrothermal alkaline alteration of metal oxides. The conversion was through a pathway of hydration-dissolution-precipitation. It involved several critical steps, including the construction of Ht from metal oxides, dissolution of Al3+ from Ht, condensation of metasilicate anions with Ht, and finally crystallization of saponite. The condensation was favored by relatively low Mg/Al ratios of Ht, along with high concentrations of Al3+ and silicate oligomers in the environment, resulting in highly crystalline saponite. The latter conversion was greatly accelerated by the isomorphous substitution of Al3+ for Si4+ in silicate oligomers. The substitution generated the extra negative charge and led to the aforementioned condensation with Ht surface, thereby promoting the formation of saponite TOT layers. During the process, CO2 is an indispensable component. Initially intercalated as CO32 CO32-to form Ht, CO2 was subsequently eliminated from the solid phase, and saponite formed when the layer charge was reversed. Thus, this study presents a novel formation mechanism of saponite from metal oxides via hydrotalcite and contributes to a better understanding of the crystallization, chemical stability, and transformation of Ht to saponite. The results are also relevant to evaluating metal availability and carbon cycling on the surface of the Earth.

Original languageEnglish (US)
Pages (from-to)1156-1164
Number of pages9
JournalAmerican Mineralogist
Volume104
Issue number8
DOIs
StatePublished - Aug 1 2019

Fingerprint

hydrotalcite
saponite
rarity
hydrothermal alteration
Oxides
metal oxides
condensation
Metals
oligomers
silicates
dissolving
substitutes
crystallization
availability
hydration
solid phases
Silicates
Condensation
Crystallization
anions

All Science Journal Classification (ASJC) codes

  • Geophysics
  • Geochemistry and Petrology

Cite this

Tao, Qi ; Zeng, Qingjin ; Chen, Manyou ; He, Hongping ; Komarneni, Sridhar. / Formation of saponite by hydrothermal alteration of metal oxides : Implication for the rarity of hydrotalcite. In: American Mineralogist. 2019 ; Vol. 104, No. 8. pp. 1156-1164.
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Formation of saponite by hydrothermal alteration of metal oxides : Implication for the rarity of hydrotalcite. / Tao, Qi; Zeng, Qingjin; Chen, Manyou; He, Hongping; Komarneni, Sridhar.

In: American Mineralogist, Vol. 104, No. 8, 01.08.2019, p. 1156-1164.

Research output: Contribution to journalArticle

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