Functional polyolefins with graft structure prepared by metallocene catalyst and p-methylstyrene comonomer

Tze-chiang Chung, H. L. Lu, W. Janvikul, R. D. Ding

Research output: Contribution to journalConference article

2 Citations (Scopus)

Abstract

The metallocene catalyst with cationic nature and spatially opened active site provides favorable condition for the incorporation of p-ms to polyolefins. The p-ms groups can be easily metallated to produce 'living' polymeric anions for graft-from polymerization. With the coexist of anion-polymerizable monomers, many graft copolymers have been prepared. The resulting graft copolymers are very effectively interfacial reagents.

Original languageEnglish (US)
Pages (from-to)248-249
Number of pages2
JournalPolymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering
Volume76
StatePublished - Jan 1 1997
EventProceedings of the 1997 Spring ACS Meeting - San Francisco, CA, USA
Duration: Apr 13 1997Apr 17 1997

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Graft copolymers
Polyolefins
Grafts
Anions
Negative ions
Catalysts
Monomers
Polymerization
PL 732
metallocene
vinyltoluene

All Science Journal Classification (ASJC) codes

  • Chemical Engineering (miscellaneous)
  • Polymers and Plastics

Cite this

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abstract = "The metallocene catalyst with cationic nature and spatially opened active site provides favorable condition for the incorporation of p-ms to polyolefins. The p-ms groups can be easily metallated to produce 'living' polymeric anions for graft-from polymerization. With the coexist of anion-polymerizable monomers, many graft copolymers have been prepared. The resulting graft copolymers are very effectively interfacial reagents.",
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AU - Chung, Tze-chiang

AU - Lu, H. L.

AU - Janvikul, W.

AU - Ding, R. D.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - The metallocene catalyst with cationic nature and spatially opened active site provides favorable condition for the incorporation of p-ms to polyolefins. The p-ms groups can be easily metallated to produce 'living' polymeric anions for graft-from polymerization. With the coexist of anion-polymerizable monomers, many graft copolymers have been prepared. The resulting graft copolymers are very effectively interfacial reagents.

AB - The metallocene catalyst with cationic nature and spatially opened active site provides favorable condition for the incorporation of p-ms to polyolefins. The p-ms groups can be easily metallated to produce 'living' polymeric anions for graft-from polymerization. With the coexist of anion-polymerizable monomers, many graft copolymers have been prepared. The resulting graft copolymers are very effectively interfacial reagents.

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M3 - Conference article

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EP - 249

JO - Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering

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