Functionalization of the Surface of Poly[bis(trifLuoroethoxy)phosphazene] by Reactions with Alkoxide Nucleophiles

Harry R. Allcock, Richard J. Fitzpatrick, Lawrence Salvati

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33 Scopus citations

Abstract

Films of poly[bis(trifluoroethoxy)phosphazene], [NP(OCH2CF3)]n, underwent surface reactions when treated with solutions of sodium alkoxides such as Na+−(OCH2CH2)xOH, where x = 1, 2, or 4; Na+−(OCH2CH2)xNH2, where x = 1 or 2; and Na+−OCH2CH2CN. The nucleophiles replaced trifluoroethoxy groups at the polymer surface without detectable side reactions. The modified surfaces were more hydrophilic than the starting material. The presence of the new surface groups was confirmed by contact-angle measurements, SEM, XPS, TEM, and ATR-IR methods. The accessibility of the surface hydroxyl and amino groups to further functionalization was confirmed by the reaction of these groups with phenyl isocyanate.

Original languageEnglish (US)
Pages (from-to)450-454
Number of pages5
JournalChemistry of Materials
Volume3
Issue number3
DOIs
StatePublished - May 1 1991

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

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