TY - JOUR
T1 - Gold(I) Vinylidene Complexes as Reactive Intermediates and Their Tendency to π-Backbond
AU - Nunes Dos Santos Comprido, Laura
AU - Klein, Johannes E.M.N.
AU - Knizia, Gerald
AU - Kästner, Johannes
AU - Hashmi, A. Stephen K.
PY - 2016/2/24
Y1 - 2016/2/24
N2 - We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.
AB - We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.
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U2 - 10.1002/chem.201504511
DO - 10.1002/chem.201504511
M3 - Article
C2 - 26711532
AN - SCOPUS:84961226333
SN - 0947-6539
VL - 22
SP - 2892
EP - 2895
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 9
ER -