HDS & deep HDS activity of Co/Mo/S-mesostructured synthetic clays

K. A. Carrado, Chunshan Song, J. H. Kim, N. Castagnola, R. Fernandez-Saavedra, C. L. Marshall, M. M. Schwartz

Research output: Contribution to journalConference articlepeer-review

1 Scopus citations

Abstract

The HDS and deep HDS activity of Co/Mo/S-mesostructured synthetic clays was studied. For HDS, the conversion of dibenzothiophene (DBT) to biphenyl was examined at 400°C using Co/Mo/S-loaded mesostructured clay supports. Activity was compared to a Crosfield 465 commercial catalyst. No hydrogenation was observed with any of the clay supports. The most active clay was derived from ludox silica sol AS-30, with an activity of 65% DBT conversion (86% for Crosfield 465). For deep HDS, the conversion of 4,6-dimethyldibenzothiophene was tested at 325° and 350°C and compared to a Criterion 344 commercial catalyst. At 325°C, Cr344 displayed 11.4% conversion. This value was nearly attained for the Co/Mo/S-loaded mesostructured clay derived from AM30 silica sol (10.5%). The commercially available synthetic hectorite called Laponite had very low activity (3%), indicating that the unique morphology of the mesostructured clays is important. Hydrogenolysis vs. hydrogenation pathways were compared for the deep HDS reaction. This is an abstract of a paper presented at the ACS Fuel Chemistry Meeting (San Diego, CA Spring 2005).

Original languageEnglish (US)
Pages (from-to)344-347
Number of pages4
JournalACS Division of Fuel Chemistry, Preprints
Volume50
Issue number1
StatePublished - Jul 26 2005

All Science Journal Classification (ASJC) codes

  • Energy(all)

Fingerprint Dive into the research topics of 'HDS & deep HDS activity of Co/Mo/S-mesostructured synthetic clays'. Together they form a unique fingerprint.

Cite this