Henry's law of adsorption on a fractal surface

Milton W. Cole, Neal S. Holter, Peter Pfeifer

Research output: Contribution to journalArticlepeer-review

55 Scopus citations

Abstract

The problem of adsorption at low coverage N on a fractal surface is addressed. General, but approximate, arguments are presented to show how the fractal dimension D is related to the Henry's-law coefficient of proportionality between N and the pressure. A semiclassical analysis validates this relation at high temperature. An evaluation for a regular fractal surface demonstrates this behavior explicitly. Relation is made to a fractal Brunauer-Emmett-Teller theory of multilayer adsorption.

Original languageEnglish (US)
Pages (from-to)8806-8809
Number of pages4
JournalPhysical Review B
Volume33
Issue number12
DOIs
StatePublished - 1986

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics

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