Hexa-1,5-diyn-3-ol ethers as tetramethynyl synthons in cobalt-catalysed acetylene co-oligomerisations; a one-step synthesis of 2,3,6,7- tetrakistrimethylsilylnaphthalene

Raymond Lee Funk, K. Peter C. Vollhardt

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Reaction of hexa-1,5-diyn-3-ol ether derivatives with bistrimethylsilylacetylene in the presence of catalytic amounts of [CpCo(CO)2] (Cp = cyclopentadienyl) gives 2,3,6,7- tetrakistrimethylsily Inaphthalene.

Original languageEnglish (US)
Pages (from-to)833-834
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number20
DOIs
StatePublished - Dec 1 1976

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Acetylene
Ethers
Cobalt
Ether
Derivatives

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

Cite this

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abstract = "Reaction of hexa-1,5-diyn-3-ol ether derivatives with bistrimethylsilylacetylene in the presence of catalytic amounts of [CpCo(CO)2] (Cp = cyclopentadienyl) gives 2,3,6,7- tetrakistrimethylsily Inaphthalene.",
author = "Funk, {Raymond Lee} and Vollhardt, {K. Peter C.}",
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AB - Reaction of hexa-1,5-diyn-3-ol ether derivatives with bistrimethylsilylacetylene in the presence of catalytic amounts of [CpCo(CO)2] (Cp = cyclopentadienyl) gives 2,3,6,7- tetrakistrimethylsily Inaphthalene.

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