High activity and stability catalysts - Kinetically frustrated ptxnanoparticles in nanoporous carbon glass

Henry C. Foley, Ramakrishnan Rajagopalan, P. Ayyapan, T. Brooks

Research output: Contribution to journalConference article

Abstract

The agglomeration and sintering of precious metals such as platinum is a costly problem across a spectrum of catalytic technologies, from those applied in the chemical and petroleum industries to that in pharmaceutical synthesis and auto exhaust catalysis. A new approach to the problem of nanoparticle stabilization, matrix entrapment, was presented. Nano particles were synthesized and incorporated into a matrix of nanoporous carbon (NPC). Reduction at 800°C in flowing hydrogen did not lead to sintering of the particles. The catalysts were quite active even at 400°C for simple reactions, e.g., olefin hydrogenations. HRTEM imaging and XRD revealed that the NPC matrix stabilizes the particles by entrapment. This led to a state that was thermodynamically unstable but for all intent and purposes persistent even under forcing conditions, hence the particles behaved as if they were "frozen" in place because the were unable to locate pathways for transport and sintering since they were too large to move through the nanopores. Hence, the system was "frustrated" kinetically from attaining lower state of chemical potential. This is an abstract of a paper presented at the 227th ACS National Meeting (Anaheim, CA 3/28/2004-4/1/2004).

Original languageEnglish (US)
JournalACS National Meeting Book of Abstracts
Volume227
Issue number2
StatePublished - Jan 1 2004
Event227th ACS National Meeting Abstracts of Papers - Anaheim, CA., United States
Duration: Mar 28 2004Apr 1 2004

Fingerprint

Sintering
Carbon
Glass
Catalysts
Nanopores
Petroleum industry
Chemical potential
Alkenes
Chemical industry
Precious metals
Platinum
Drug products
Catalysis
Olefins
Hydrogenation
Hydrogen
Agglomeration
Stabilization
Nanoparticles
Imaging techniques

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

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title = "High activity and stability catalysts - Kinetically frustrated ptxnanoparticles in nanoporous carbon glass",
abstract = "The agglomeration and sintering of precious metals such as platinum is a costly problem across a spectrum of catalytic technologies, from those applied in the chemical and petroleum industries to that in pharmaceutical synthesis and auto exhaust catalysis. A new approach to the problem of nanoparticle stabilization, matrix entrapment, was presented. Nano particles were synthesized and incorporated into a matrix of nanoporous carbon (NPC). Reduction at 800°C in flowing hydrogen did not lead to sintering of the particles. The catalysts were quite active even at 400°C for simple reactions, e.g., olefin hydrogenations. HRTEM imaging and XRD revealed that the NPC matrix stabilizes the particles by entrapment. This led to a state that was thermodynamically unstable but for all intent and purposes persistent even under forcing conditions, hence the particles behaved as if they were {"}frozen{"} in place because the were unable to locate pathways for transport and sintering since they were too large to move through the nanopores. Hence, the system was {"}frustrated{"} kinetically from attaining lower state of chemical potential. This is an abstract of a paper presented at the 227th ACS National Meeting (Anaheim, CA 3/28/2004-4/1/2004).",
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High activity and stability catalysts - Kinetically frustrated ptxnanoparticles in nanoporous carbon glass. / Foley, Henry C.; Rajagopalan, Ramakrishnan; Ayyapan, P.; Brooks, T.

In: ACS National Meeting Book of Abstracts, Vol. 227, No. 2, 01.01.2004.

Research output: Contribution to journalConference article

TY - JOUR

T1 - High activity and stability catalysts - Kinetically frustrated ptxnanoparticles in nanoporous carbon glass

AU - Foley, Henry C.

AU - Rajagopalan, Ramakrishnan

AU - Ayyapan, P.

AU - Brooks, T.

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Y1 - 2004/1/1

N2 - The agglomeration and sintering of precious metals such as platinum is a costly problem across a spectrum of catalytic technologies, from those applied in the chemical and petroleum industries to that in pharmaceutical synthesis and auto exhaust catalysis. A new approach to the problem of nanoparticle stabilization, matrix entrapment, was presented. Nano particles were synthesized and incorporated into a matrix of nanoporous carbon (NPC). Reduction at 800°C in flowing hydrogen did not lead to sintering of the particles. The catalysts were quite active even at 400°C for simple reactions, e.g., olefin hydrogenations. HRTEM imaging and XRD revealed that the NPC matrix stabilizes the particles by entrapment. This led to a state that was thermodynamically unstable but for all intent and purposes persistent even under forcing conditions, hence the particles behaved as if they were "frozen" in place because the were unable to locate pathways for transport and sintering since they were too large to move through the nanopores. Hence, the system was "frustrated" kinetically from attaining lower state of chemical potential. This is an abstract of a paper presented at the 227th ACS National Meeting (Anaheim, CA 3/28/2004-4/1/2004).

AB - The agglomeration and sintering of precious metals such as platinum is a costly problem across a spectrum of catalytic technologies, from those applied in the chemical and petroleum industries to that in pharmaceutical synthesis and auto exhaust catalysis. A new approach to the problem of nanoparticle stabilization, matrix entrapment, was presented. Nano particles were synthesized and incorporated into a matrix of nanoporous carbon (NPC). Reduction at 800°C in flowing hydrogen did not lead to sintering of the particles. The catalysts were quite active even at 400°C for simple reactions, e.g., olefin hydrogenations. HRTEM imaging and XRD revealed that the NPC matrix stabilizes the particles by entrapment. This led to a state that was thermodynamically unstable but for all intent and purposes persistent even under forcing conditions, hence the particles behaved as if they were "frozen" in place because the were unable to locate pathways for transport and sintering since they were too large to move through the nanopores. Hence, the system was "frustrated" kinetically from attaining lower state of chemical potential. This is an abstract of a paper presented at the 227th ACS National Meeting (Anaheim, CA 3/28/2004-4/1/2004).

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