TY - JOUR
T1 - High Curie temperature perovskite BiInO3-PbTiO3 ceramics
AU - Duan, Runrun
AU - Speyer, Robert F.
AU - Alberta, Edward
AU - Shrout, Thomas R.
PY - 2004/7/1
Y1 - 2004/7/1
N2 - The extent of BiInO3 substitution in the perovskite system xBiInO3-(1 - x)PbTiO3 and the corresponding raise in the Curie temperature were investigated-using thermal analysis, dielectric measurements, x-ray diffraction, and electron microscopy. Maximum tetragonal perovskite distortion (c/a = 1.082) was obtained for x = 0.20, with a corresponding Curie temperature of 582 °C. Phase-pure tetragonal perovskite was obtained for x ≤ 0.25. Compound formation after calcining mixed oxide powders resulted in agglomerated cube-shaped tetragonal perovskite particles, which could be fired to 94.7% of theoretical density (TD). Sol-gel fabrication resulted in nano-sized tetragonal or pseudo-cubic perovskite particles, which after two-step firing, resulted in tetragonal perovskite microstructure at as high as (x = 0.20) 98.1% of TD.
AB - The extent of BiInO3 substitution in the perovskite system xBiInO3-(1 - x)PbTiO3 and the corresponding raise in the Curie temperature were investigated-using thermal analysis, dielectric measurements, x-ray diffraction, and electron microscopy. Maximum tetragonal perovskite distortion (c/a = 1.082) was obtained for x = 0.20, with a corresponding Curie temperature of 582 °C. Phase-pure tetragonal perovskite was obtained for x ≤ 0.25. Compound formation after calcining mixed oxide powders resulted in agglomerated cube-shaped tetragonal perovskite particles, which could be fired to 94.7% of theoretical density (TD). Sol-gel fabrication resulted in nano-sized tetragonal or pseudo-cubic perovskite particles, which after two-step firing, resulted in tetragonal perovskite microstructure at as high as (x = 0.20) 98.1% of TD.
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U2 - 10.1557/JMR.2004.0282
DO - 10.1557/JMR.2004.0282
M3 - Article
AN - SCOPUS:4143049131
VL - 19
SP - 2185
EP - 2193
JO - Journal of Materials Research
JF - Journal of Materials Research
SN - 0884-2914
IS - 7
ER -