High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating

Guangyuan Zheng, Chao Wang, Allen Pei, Jeffrey Lopez, Feifei Shi, Zheng Chen, Austin D. Sendek, Hyun Wook Lee, Zhenda Lu, Holger Schneider, Marina M. Safont-Sempere, Steven Chu, Zhenan Bao, Yi Cui

Research output: Contribution to journalArticle

100 Citations (Scopus)

Abstract

The future development of low-cost, high-performance electric vehicles depends on the success of next-generation lithium-ion batteries with higher energy density. The lithium metal negative electrode is key to applying these new battery technologies. However, the problems of lithium dendrite growth and low Coulombic efficiency have proven to be difficult challenges to overcome. Fundamentally, these two issues stem from the instability of the solid electrolyte interphase (SEI) layer, which is easily damaged by the large volumetric changes during battery cycling. In this work, we show that when a highly viscoelastic polymer was applied to the lithium metal electrode, the morphology of the lithium deposition became significantly more uniform. At a high current density of 5 mA/cm2 we obtained a flat and dense lithium metal layer, and we observed stable cycling Coulombic efficiency of ∼97% maintained for more than 180 cycles at a current density of 1 mA/cm2.

Original languageEnglish (US)
Pages (from-to)1247-1255
Number of pages9
JournalACS Energy Letters
Volume1
Issue number6
DOIs
StatePublished - Dec 9 2016

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Lithium
Polymers
Metals
Coatings
Electrodes
Current density
Solid electrolytes
Electric vehicles
Costs

All Science Journal Classification (ASJC) codes

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

Cite this

Zheng, Guangyuan ; Wang, Chao ; Pei, Allen ; Lopez, Jeffrey ; Shi, Feifei ; Chen, Zheng ; Sendek, Austin D. ; Lee, Hyun Wook ; Lu, Zhenda ; Schneider, Holger ; Safont-Sempere, Marina M. ; Chu, Steven ; Bao, Zhenan ; Cui, Yi. / High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating. In: ACS Energy Letters. 2016 ; Vol. 1, No. 6. pp. 1247-1255.
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Zheng, G, Wang, C, Pei, A, Lopez, J, Shi, F, Chen, Z, Sendek, AD, Lee, HW, Lu, Z, Schneider, H, Safont-Sempere, MM, Chu, S, Bao, Z & Cui, Y 2016, 'High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating', ACS Energy Letters, vol. 1, no. 6, pp. 1247-1255. https://doi.org/10.1021/acsenergylett.6b00456

High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating. / Zheng, Guangyuan; Wang, Chao; Pei, Allen; Lopez, Jeffrey; Shi, Feifei; Chen, Zheng; Sendek, Austin D.; Lee, Hyun Wook; Lu, Zhenda; Schneider, Holger; Safont-Sempere, Marina M.; Chu, Steven; Bao, Zhenan; Cui, Yi.

In: ACS Energy Letters, Vol. 1, No. 6, 09.12.2016, p. 1247-1255.

Research output: Contribution to journalArticle

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AU - Sendek, Austin D.

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