High resolution spectroscopy and channel-coupling treatment of the A1Σ+-b3∏ complex of NaRb

M. Tamanis, R. Ferber, A. Zaitsevskii, E. A. Pazyuk, A. V. Stolyarov, Hongmin Chen, Jianbing Qi, Henry Wang, William C. Stwalley

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

The fully mixed complex of the NaRb molecule based on high-resolution sub-Doppler spectroscopy and intensity measurements was studied. A two-laser V-type pump-probe excitation scheme was used to obtain A←X transition frequencies to 16 A-state vibrational levels from v=6 to v=21 with J from 8 to 23. It was shown that the inverted channel-coupling approach was useful in deperturbation analysis of strongly coupled electronic states.

Original languageEnglish (US)
Pages (from-to)7980-7988
Number of pages9
JournalJournal of Chemical Physics
Volume117
Issue number17
DOIs
StatePublished - Nov 1 2002

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Electronic states
vibrational states
Pumps
Spectroscopy
pumps
Molecules
Lasers
probes
high resolution
electronics
spectroscopy
excitation
lasers
molecules

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Tamanis, M., Ferber, R., Zaitsevskii, A., Pazyuk, E. A., Stolyarov, A. V., Chen, H., ... Stwalley, W. C. (2002). High resolution spectroscopy and channel-coupling treatment of the A1Σ+-b3∏ complex of NaRb. Journal of Chemical Physics, 117(17), 7980-7988. https://doi.org/10.1063/1.1505442
Tamanis, M. ; Ferber, R. ; Zaitsevskii, A. ; Pazyuk, E. A. ; Stolyarov, A. V. ; Chen, Hongmin ; Qi, Jianbing ; Wang, Henry ; Stwalley, William C. / High resolution spectroscopy and channel-coupling treatment of the A1Σ+-b3∏ complex of NaRb. In: Journal of Chemical Physics. 2002 ; Vol. 117, No. 17. pp. 7980-7988.
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Tamanis, M, Ferber, R, Zaitsevskii, A, Pazyuk, EA, Stolyarov, AV, Chen, H, Qi, J, Wang, H & Stwalley, WC 2002, 'High resolution spectroscopy and channel-coupling treatment of the A1Σ+-b3∏ complex of NaRb', Journal of Chemical Physics, vol. 117, no. 17, pp. 7980-7988. https://doi.org/10.1063/1.1505442

High resolution spectroscopy and channel-coupling treatment of the A1Σ+-b3∏ complex of NaRb. / Tamanis, M.; Ferber, R.; Zaitsevskii, A.; Pazyuk, E. A.; Stolyarov, A. V.; Chen, Hongmin; Qi, Jianbing; Wang, Henry; Stwalley, William C.

In: Journal of Chemical Physics, Vol. 117, No. 17, 01.11.2002, p. 7980-7988.

Research output: Contribution to journalArticle

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AU - Tamanis, M.

AU - Ferber, R.

AU - Zaitsevskii, A.

AU - Pazyuk, E. A.

AU - Stolyarov, A. V.

AU - Chen, Hongmin

AU - Qi, Jianbing

AU - Wang, Henry

AU - Stwalley, William C.

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Tamanis M, Ferber R, Zaitsevskii A, Pazyuk EA, Stolyarov AV, Chen H et al. High resolution spectroscopy and channel-coupling treatment of the A1Σ+-b3∏ complex of NaRb. Journal of Chemical Physics. 2002 Nov 1;117(17):7980-7988. https://doi.org/10.1063/1.1505442