TY - JOUR
T1 - HIGH TEMPERATURE REACTIONS BETWEEN HEXACHLOROCYCLOTRIPHOSPHAZENE AND HEXAMETHYLCYCLOTRISILOXANE.
AU - Brennan, David J.
AU - Allen, Robert W.
AU - Allcock, Harry R.
PY - 1984/8/1
Y1 - 1984/8/1
N2 - Hexachlorocyclotriphosphazene undergoes a thermally induced ring-opening polymerization at temperatures above 210 degree C. Hexamethylcyclotrisiloxane also polymerizes at elevated temperatures, especially when an acidic or basic catalyst is used. Similarities exist between the mechanisms of polymerization for the two cyclic species. Since these two mechanisms are similar, it is possible that a polymerization or interaction could occur. Experiments were thus carried out to determine how the compounds reacted under conditions for thermal polymerization.
AB - Hexachlorocyclotriphosphazene undergoes a thermally induced ring-opening polymerization at temperatures above 210 degree C. Hexamethylcyclotrisiloxane also polymerizes at elevated temperatures, especially when an acidic or basic catalyst is used. Similarities exist between the mechanisms of polymerization for the two cyclic species. Since these two mechanisms are similar, it is possible that a polymerization or interaction could occur. Experiments were thus carried out to determine how the compounds reacted under conditions for thermal polymerization.
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M3 - Conference article
AN - SCOPUS:0021480795
VL - 25
SP - 122
EP - 123
JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
SN - 0032-3934
IS - 2
ER -