Abstract
Hexachlorocyclotriphosphazene undergoes a thermally induced ring-opening polymerization at temperatures above 210 degree C. Hexamethylcyclotrisiloxane also polymerizes at elevated temperatures, especially when an acidic or basic catalyst is used. Similarities exist between the mechanisms of polymerization for the two cyclic species. Since these two mechanisms are similar, it is possible that a polymerization or interaction could occur. Experiments were thus carried out to determine how the compounds reacted under conditions for thermal polymerization.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 122-123 |
| Number of pages | 2 |
| Journal | American Chemical Society, Polymer Preprints, Division of Polymer Chemistry |
| Volume | 25 |
| Issue number | 2 |
| State | Published - Aug 1 1984 |
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All Science Journal Classification (ASJC) codes
- Polymers and Plastics
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HIGH TEMPERATURE REACTIONS BETWEEN HEXACHLOROCYCLOTRIPHOSPHAZENE AND HEXAMETHYLCYCLOTRISILOXANE. / Brennan, David J.; Allen, Robert W.; Allcock, Harry R.
In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 25, No. 2, 01.08.1984, p. 122-123.Research output: Contribution to journal › Conference article
TY - JOUR
T1 - HIGH TEMPERATURE REACTIONS BETWEEN HEXACHLOROCYCLOTRIPHOSPHAZENE AND HEXAMETHYLCYCLOTRISILOXANE.
AU - Brennan, David J.
AU - Allen, Robert W.
AU - Allcock, Harry R.
PY - 1984/8/1
Y1 - 1984/8/1
N2 - Hexachlorocyclotriphosphazene undergoes a thermally induced ring-opening polymerization at temperatures above 210 degree C. Hexamethylcyclotrisiloxane also polymerizes at elevated temperatures, especially when an acidic or basic catalyst is used. Similarities exist between the mechanisms of polymerization for the two cyclic species. Since these two mechanisms are similar, it is possible that a polymerization or interaction could occur. Experiments were thus carried out to determine how the compounds reacted under conditions for thermal polymerization.
AB - Hexachlorocyclotriphosphazene undergoes a thermally induced ring-opening polymerization at temperatures above 210 degree C. Hexamethylcyclotrisiloxane also polymerizes at elevated temperatures, especially when an acidic or basic catalyst is used. Similarities exist between the mechanisms of polymerization for the two cyclic species. Since these two mechanisms are similar, it is possible that a polymerization or interaction could occur. Experiments were thus carried out to determine how the compounds reacted under conditions for thermal polymerization.
UR - http://www.scopus.com/inward/record.url?scp=0021480795&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0021480795&partnerID=8YFLogxK
M3 - Conference article
AN - SCOPUS:0021480795
VL - 25
SP - 122
EP - 123
JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
SN - 0032-3934
IS - 2
ER -