High-Voltage Stability of Ionic-Liquid-Based Electrochemical Double Layer Capacitors with a Bimodal Porous Carbon Electrode

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Abstract

Micropores (<2 nm) and small mesopores (width between 2 and 10 nm) in the structure of carbon play an important role in determining both the charge storage properties and voltage stability of ionic-liquid-based electrochemical double layer capacitors (EDLCs). We demonstrate that the use of bimodal porous carbon electrodes results in excellent voltage stability and good capacitance retention (>90 %), as determined by using voltage holding tests at 3.5 V over 250 h. Furthermore, a three-electrode split cell study showed that the voltage stability in bimodal carbon was achieved because of more symmetric potential distribution and similar electrode capacitances between the positive and negative electrodes as compared to purely microporous carbon electrode. The presence of larger mesopores (5–10 nm) in the bimodal carbon facilitates the access and rearrangement of the bulkier cations at the electrode/electrolyte interface, whereas this is severely hindered in purely microporous carbon electrode. By using a lumped transmission line model, we delineated the contribution of both smaller and larger pores in the bimodal carbon towards the impedance performance of EDLCs.

Original languageEnglish (US)
Pages (from-to)3460-3467
Number of pages8
JournalChemElectroChem
Volume5
Issue number22
DOIs
StatePublished - Nov 13 2018

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Ionic Liquids
Ionic liquids
Voltage control
Capacitors
Carbon
Electrodes
Electrolytes
Cations
Electric lines
Capacitance
Positive ions
Electric potential

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electrochemistry

Cite this

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title = "High-Voltage Stability of Ionic-Liquid-Based Electrochemical Double Layer Capacitors with a Bimodal Porous Carbon Electrode",
abstract = "Micropores (<2 nm) and small mesopores (width between 2 and 10 nm) in the structure of carbon play an important role in determining both the charge storage properties and voltage stability of ionic-liquid-based electrochemical double layer capacitors (EDLCs). We demonstrate that the use of bimodal porous carbon electrodes results in excellent voltage stability and good capacitance retention (>90 {\%}), as determined by using voltage holding tests at 3.5 V over 250 h. Furthermore, a three-electrode split cell study showed that the voltage stability in bimodal carbon was achieved because of more symmetric potential distribution and similar electrode capacitances between the positive and negative electrodes as compared to purely microporous carbon electrode. The presence of larger mesopores (5–10 nm) in the bimodal carbon facilitates the access and rearrangement of the bulkier cations at the electrode/electrolyte interface, whereas this is severely hindered in purely microporous carbon electrode. By using a lumped transmission line model, we delineated the contribution of both smaller and larger pores in the bimodal carbon towards the impedance performance of EDLCs.",
author = "Aref, {Amir Reza} and Ramakrishnan Rajagopalan and Randall, {Clive A.}",
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AU - Aref, Amir Reza

AU - Rajagopalan, Ramakrishnan

AU - Randall, Clive A.

PY - 2018/11/13

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N2 - Micropores (<2 nm) and small mesopores (width between 2 and 10 nm) in the structure of carbon play an important role in determining both the charge storage properties and voltage stability of ionic-liquid-based electrochemical double layer capacitors (EDLCs). We demonstrate that the use of bimodal porous carbon electrodes results in excellent voltage stability and good capacitance retention (>90 %), as determined by using voltage holding tests at 3.5 V over 250 h. Furthermore, a three-electrode split cell study showed that the voltage stability in bimodal carbon was achieved because of more symmetric potential distribution and similar electrode capacitances between the positive and negative electrodes as compared to purely microporous carbon electrode. The presence of larger mesopores (5–10 nm) in the bimodal carbon facilitates the access and rearrangement of the bulkier cations at the electrode/electrolyte interface, whereas this is severely hindered in purely microporous carbon electrode. By using a lumped transmission line model, we delineated the contribution of both smaller and larger pores in the bimodal carbon towards the impedance performance of EDLCs.

AB - Micropores (<2 nm) and small mesopores (width between 2 and 10 nm) in the structure of carbon play an important role in determining both the charge storage properties and voltage stability of ionic-liquid-based electrochemical double layer capacitors (EDLCs). We demonstrate that the use of bimodal porous carbon electrodes results in excellent voltage stability and good capacitance retention (>90 %), as determined by using voltage holding tests at 3.5 V over 250 h. Furthermore, a three-electrode split cell study showed that the voltage stability in bimodal carbon was achieved because of more symmetric potential distribution and similar electrode capacitances between the positive and negative electrodes as compared to purely microporous carbon electrode. The presence of larger mesopores (5–10 nm) in the bimodal carbon facilitates the access and rearrangement of the bulkier cations at the electrode/electrolyte interface, whereas this is severely hindered in purely microporous carbon electrode. By using a lumped transmission line model, we delineated the contribution of both smaller and larger pores in the bimodal carbon towards the impedance performance of EDLCs.

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