Homogeneously dispersed CeO2 nanoparticles on exfoliated hexaniobate nanosheets

Thalles M.F. Marques, Megan E. Strayer, Anupama Ghosh, Alexandre Silva, Odair P. Ferreira, Kazunori Fujisawa, Jose R. Alves da Cunha, Guilherme J.P. Abreu, Mauricio Terrones, Thomas E. Mallouk, Bartolomeu C. Viana

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

Hexaniobate nanosheets derived from the parent compound K4Nb6O17 have been decorated with CeO2 nanoparticles by ion exchange with aqueous cerium (IV) solution. Very homogeneous CeO2 nanoparticle decoration of the hexaniobate sheets can be achieved by this method and the resulting composites may absorb visible light. HRTEM images show that ∼3.0 nm diameter CeO2 nanoparticles adhere to hexaniobate nanosheets that are exfoliated and then restacked prior to Ce deposition. The interfacial interaction between CeO2 nanoparticles and nanosheets would be due to an electrostatic attraction mechanism. Raman and XRD measurements have given strong evidence that CeO2 nanoparticles have fluorite structure. EDS, FTIR and XPS results suggest almost complete exchange of TBA+ and K+ by Ce4+. Cerium ion exchange on the acid exchanged parent compound, H2.9K1.1Nb6O17, revealed that the extent of Ce ion exchange is much greater in case of nanosheets, which may be rationalized by the larger surface area available after exfoliation. XPS measurements show that the ratio of Ce4+/Ce3+ is around 4.4, in agreement with the formation of fluorite structure (CeO2). Thus, these CeO2 nanoparticle/nanosheet composites may be useful for catalytic processes.

Original languageEnglish (US)
Pages (from-to)335-342
Number of pages8
JournalJournal of Physics and Chemistry of Solids
Volume111
DOIs
StatePublished - Dec 2017

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'Homogeneously dispersed CeO<sub>2</sub> nanoparticles on exfoliated hexaniobate nanosheets'. Together they form a unique fingerprint.

  • Cite this

    Marques, T. M. F., Strayer, M. E., Ghosh, A., Silva, A., Ferreira, O. P., Fujisawa, K., Alves da Cunha, J. R., Abreu, G. J. P., Terrones, M., Mallouk, T. E., & Viana, B. C. (2017). Homogeneously dispersed CeO2 nanoparticles on exfoliated hexaniobate nanosheets. Journal of Physics and Chemistry of Solids, 111, 335-342. https://doi.org/10.1016/j.jpcs.2017.08.027