How copolymers promote mixing of immiscible homopolymers

Scott T. Milner, Haowen Xi

Research output: Contribution to journalArticle

162 Scopus citations

Abstract

Copolymers and stirring are commonly used to produce fine dispersions of immiscible homopolymers. Recent experiments cell into questions the classical view that copolymers promote the mixing by reducing the interfacial tension, suggesting rather that copolymers induce repulsive interactions between droplets and thus inhibit collision-induced coalescence events. We present a dynamical theory of the breakup and coalescence of polymer droplets in a mixing shear flow, including hydrodynamic and repulsive interactions between droplets. We find that a low surface coverage of copolymers, of the order of one chain per square radius of gyration, is sufficient to inhibit collisions between submicron-sized droplets, while giving a negligible reduction in interfacial tension.

Original languageEnglish (US)
Pages (from-to)663-687
Number of pages25
JournalJournal of Rheology
Volume40
Issue number4
DOIs
StatePublished - Jan 1 1996

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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