Hybrid zeolite-supported Pd catalyst with high sulfur tolerance for low-temperature hydrogenation of aromatics in diesel fuels

Hyun Jae Kim, Chunshan Song

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Zeolite-supported noble metals are potential catalysts for the low-temperature hydrogenation of aromatics in distillate fuels for producing ultra clean diesel fuels, but sulfur poisoning remains a major problem to be solved. In this study, hybrid catalyst was prepared as shape-selective and sulfur-tolerant noble metal catalyst using two zeolite supports having two different pore channel sizes (zeolite Y and A) based on our proposed new concept for catalyst design [CS Song, Chemtech, 1999, 29 (3), 26-30]. The hybrid catalyst have two different functions, hydrogenation in large-pore microporous channel such as that of Y zeolite and hydrogen spillover in small-pore microporous channels such as Zeolote A. It was found that zeolite A supported Pd catalyst itself did not show any significant catalytic activity for hydrogenation, but helped the zeolite Y supported Pd catalyst maintain the high activity of hydrogenation of tetralin by hydrogen spillover in the presence of sulfur compounds at low temperatures. Pd clusters on the external surface of Zeolite A supported Pd catalysts were passivated by chemical vapor deposition (CVD) with tetraethyl orthosilicate (TEOS) to clarify the effect of the catalytic functions and hydrogen spillover inside the small micropore of the hybrid catalyst system.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society - 235th National Meeting, Abstracts of Scientific Papers
StatePublished - Dec 1 2008
Event235th National Meeting of the American Chemical Society, ACS 2008 - New Orleans, LA, United States
Duration: Apr 6 2008Apr 10 2008

Publication series

NameACS National Meeting Book of Abstracts
ISSN (Print)0065-7727

Other

Other235th National Meeting of the American Chemical Society, ACS 2008
CountryUnited States
CityNew Orleans, LA
Period4/6/084/10/08

Fingerprint

Zeolites
Diesel fuels
Sulfur
Catalyst supports
Hydrogenation
Catalysts
Hydrogen
Precious metals
Temperature
Sulfur compounds
Sulfur Compounds
Chemical vapor deposition
Catalyst activity

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Kim, H. J., & Song, C. (2008). Hybrid zeolite-supported Pd catalyst with high sulfur tolerance for low-temperature hydrogenation of aromatics in diesel fuels. In American Chemical Society - 235th National Meeting, Abstracts of Scientific Papers (ACS National Meeting Book of Abstracts).
Kim, Hyun Jae ; Song, Chunshan. / Hybrid zeolite-supported Pd catalyst with high sulfur tolerance for low-temperature hydrogenation of aromatics in diesel fuels. American Chemical Society - 235th National Meeting, Abstracts of Scientific Papers. 2008. (ACS National Meeting Book of Abstracts).
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Kim, HJ & Song, C 2008, Hybrid zeolite-supported Pd catalyst with high sulfur tolerance for low-temperature hydrogenation of aromatics in diesel fuels. in American Chemical Society - 235th National Meeting, Abstracts of Scientific Papers. ACS National Meeting Book of Abstracts, 235th National Meeting of the American Chemical Society, ACS 2008, New Orleans, LA, United States, 4/6/08.

Hybrid zeolite-supported Pd catalyst with high sulfur tolerance for low-temperature hydrogenation of aromatics in diesel fuels. / Kim, Hyun Jae; Song, Chunshan.

American Chemical Society - 235th National Meeting, Abstracts of Scientific Papers. 2008. (ACS National Meeting Book of Abstracts).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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Kim HJ, Song C. Hybrid zeolite-supported Pd catalyst with high sulfur tolerance for low-temperature hydrogenation of aromatics in diesel fuels. In American Chemical Society - 235th National Meeting, Abstracts of Scientific Papers. 2008. (ACS National Meeting Book of Abstracts).