TY - JOUR
T1 - Hydrodeoxygenation of Guaiacol Catalyzed by High-Loading Ni Catalysts Supported on SiO2-TiO2 Binary Oxides
AU - Lu, Mohong
AU - Sun, Yu
AU - Zhang, Peng
AU - Zhu, Jie
AU - Li, Mingshi
AU - Shan, Yuhua
AU - Shen, Jianyi
AU - Song, Chunshan
N1 - Funding Information:
This work was financially supported by the National Natural Science Foundation of China (Grants 21761132006 and 21676029). The authors also acknowledge the Natural Science Foundation of Jiangsu Higher Education Institutions (Grant 12KJB530001) and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) for the financial support.
PY - 2019/1/30
Y1 - 2019/1/30
N2 - A series of SiO2-TiO2 binary oxides supported high loading Ni catalysts were prepared using the co-precipitation method and tested in guaiacol hydrodeoxygenation (HDO). The catalysts were characterized using N2 adsorption-desorption, XRD, TEM, FT-IR, XPS, H2-TPD, and NH3-TPD. The formation of Si-O-Ti bond in the SiO2-TiO2 binary oxides was verified by XPS, which can increase the total amount of acidic sites and enhance the interaction between metal Ni and TiO2. The oxygen defect sites of TiO2 were formed near the perimeter of the metal-support interface, leading to generation of Niδ--OV-Ti3+ interface sites, which play the role of active centers to catalyze guaiacol HDO. These positive factors promoted HDO activity over Ni catalysts supported on binary oxides, compared to Ni loaded on single oxide supports. The selectivity of products indicates relatively high temperature and low H2 pressure are beneficial for producing oxygen-free aromatics in HDO of guaiacol.
AB - A series of SiO2-TiO2 binary oxides supported high loading Ni catalysts were prepared using the co-precipitation method and tested in guaiacol hydrodeoxygenation (HDO). The catalysts were characterized using N2 adsorption-desorption, XRD, TEM, FT-IR, XPS, H2-TPD, and NH3-TPD. The formation of Si-O-Ti bond in the SiO2-TiO2 binary oxides was verified by XPS, which can increase the total amount of acidic sites and enhance the interaction between metal Ni and TiO2. The oxygen defect sites of TiO2 were formed near the perimeter of the metal-support interface, leading to generation of Niδ--OV-Ti3+ interface sites, which play the role of active centers to catalyze guaiacol HDO. These positive factors promoted HDO activity over Ni catalysts supported on binary oxides, compared to Ni loaded on single oxide supports. The selectivity of products indicates relatively high temperature and low H2 pressure are beneficial for producing oxygen-free aromatics in HDO of guaiacol.
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U2 - 10.1021/acs.iecr.8b04517
DO - 10.1021/acs.iecr.8b04517
M3 - Article
AN - SCOPUS:85060389613
VL - 58
SP - 1513
EP - 1524
JO - Industrial and Engineering Chemistry Research
JF - Industrial and Engineering Chemistry Research
SN - 0888-5885
IS - 4
ER -