Hydrogen bond breaking probed with multidimensional stimulated vibrational echo correlation spectroscopy

John B. Asbury, Tobias Steinel, C. Stromberg, K. J. Gaffney, I. R. Piletic, M. D. Fayer

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Abstract

The results of vibrational echo correlation spectroscopy with full phase information were used to examine aspects of the hydrogen bond dynamics of methanol-OD in CCl4. By using extremely short pulses, it was possible to excite the entire very broad hydroxyl-stretching band including the 1-2 transition. Vibrational echo correlation spectroscopy combined with detailed calculations made it possible to explicate the population dynamics of hydrogen bond evolution with considerable clarity and detail.

Original languageEnglish (US)
Pages (from-to)12981-12997
Number of pages17
JournalJournal of Chemical Physics
Volume119
Issue number24
DOIs
StatePublished - Dec 22 2003

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All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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