Hydrogen storage via hydrogen spillover to nanoporous materials

Angela Lueking, Qixiu Li

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Hydrogen storage in nanoporous materials can be increased by hydrogen spillover from a supported catalyst to the high-surface area support. The process increases the active temperature of adsorption to the nanoporous support, typically to moderate temperatures (i.e. 300K). The overall surface coverage of hydrogen can be optimized by enhancing the rate of spillover from the catalyst to the nanoporous support and/or increasing the binding energy of atomic hydrogen to specialized surface binding sites. The pressure dependence of hydrogen spillover, the effect of surface chemistry, porosity, metal-support interface, and catalyst loading will be discussed. New results using carbide-derived-carbons, tailored activated carbons, and metal-organic frameworks will be discussed.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society - 237th National Meeting and Exposition, ACS 2009, Abstracts of Scientific Papers
StatePublished - Dec 1 2009
Event237th National Meeting and Exposition of the American Chemical Society, ACS 2009 - Salt Lake City, UT, United States
Duration: Mar 22 2009Mar 26 2009

Publication series

NameACS National Meeting Book of Abstracts
ISSN (Print)0065-7727

Other

Other237th National Meeting and Exposition of the American Chemical Society, ACS 2009
CountryUnited States
CitySalt Lake City, UT
Period3/22/093/26/09

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Lueking, A., & Li, Q. (2009). Hydrogen storage via hydrogen spillover to nanoporous materials. In American Chemical Society - 237th National Meeting and Exposition, ACS 2009, Abstracts of Scientific Papers (ACS National Meeting Book of Abstracts).