Hydrothermal liquefaction of Nannochloropsis sp.

Systematic study of process variables and analysis of the product fractions

Peter J. Valdez, Michael C. Nelson, Henry Y. Wang, Xiaoxia Nina Lin, Phillip E. Savage

Research output: Contribution to journalArticle

201 Citations (Scopus)

Abstract

We investigated hydrothermal liquefaction of Nannochloropsis sp. at different temperatures (250-400 °C), times (10-90 min), water densities (0.3-0.5 g/mL), and biomass loadings (5-35 wt %). Liquefaction produced a biocrude with light and heavy fractions, along with gaseous, aqueous, and solid by-product fractions. The gravimetric yields of the product fractions from experiments at 250 °C summed to an average of 100 ± 4 wt %, showing mass balance closure at 250 °C. The gravimetric yields of the product fractions are independent of water density at 400 °C. Increasing the biomass loading increases the biocrude yield from 36 to 46 wt %. The yields of light and heavy biocrude depend on reaction time and temperature, but their combined yield depends primarily on temperature. Regardless of reaction time and temperature, the yield of products distributed to the aqueous phase is 51 ± 5 wt % and the light biocrude is 75 ± 1 wt % C. Two-thirds of the N in the alga is immediately distributed to the aqueous phase and up to 84% can be partitioned there. Up to 85% of the P is distributed to the aqueous phase in the form of free phosphate. Thus, N and P can be recovered in the aqueous phase for nutrient recycling. Up to 80% of the chemical energy in the alga is retained within the biocrude. The quantitative results reported herein provide the basis for a reaction network for algae liquefaction.

Original languageEnglish (US)
Pages (from-to)317-331
Number of pages15
JournalBiomass and Bioenergy
Volume46
DOIs
StatePublished - Nov 1 2012

Fingerprint

Nannochloropsis
Liquefaction
liquefaction
algae
Algae
Biomass
water
alga
Temperature
temperature
Nutrients
Byproducts
Recycling
Water
Phosphates
biomass
product
analysis
mass balance
recycling

All Science Journal Classification (ASJC) codes

  • Agronomy and Crop Science
  • Forestry
  • Renewable Energy, Sustainability and the Environment
  • Waste Management and Disposal

Cite this

Valdez, Peter J. ; Nelson, Michael C. ; Wang, Henry Y. ; Lin, Xiaoxia Nina ; Savage, Phillip E. / Hydrothermal liquefaction of Nannochloropsis sp. Systematic study of process variables and analysis of the product fractions. In: Biomass and Bioenergy. 2012 ; Vol. 46. pp. 317-331.
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Hydrothermal liquefaction of Nannochloropsis sp. Systematic study of process variables and analysis of the product fractions. / Valdez, Peter J.; Nelson, Michael C.; Wang, Henry Y.; Lin, Xiaoxia Nina; Savage, Phillip E.

In: Biomass and Bioenergy, Vol. 46, 01.11.2012, p. 317-331.

Research output: Contribution to journalArticle

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