Hydrothermal synthesis of Zn-smectites

Shoji Higashi, Kazuhiko Miki, Sridhar Komarneni

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22 Scopus citations


Two varieties of Zn-smectite were synthesized hydrothermally: sauconite, with an ideal composition of hectorite, with an ideal composition of Na0.4 (Li0.4Zn2.6)Si4O10(OH)2·nH2O (referred to here as Zn-hectorite). For comparison, hydrothermal synthesis of the related trioctahedral smectites of hectorite, Na0.4(Li0.4Mg2.6)Si4O10(OH)2·nH2O and hectorites containing Cu, Co or Ni in the octahedral sheets instead of Mg were also attempted. The results showed that sauconite, Zn-hectorite and hectorite could be synthesized in the temperature range 100-125°C but hectorites containing Cu, Co or Ni in the octahedral sheet, under the same conditions or even at a temperature of 150°C, could not.

Original languageEnglish (US)
Pages (from-to)299-305
Number of pages7
JournalClays and Clay Minerals
Issue number3
StatePublished - Jun 1 2002

All Science Journal Classification (ASJC) codes

  • Water Science and Technology
  • Soil Science
  • Geochemistry and Petrology
  • Earth and Planetary Sciences (miscellaneous)


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