In situ structure characterization of Pb(Yb 1/2Nb 1/2)O 3-PbTiO 3 crystals under high pressure-temperature

Lingping Kong, Luhong Wang, Shujun Zhang, Oliver Tschauner, Yusheng Zhao, Wenge Yang, Haozhe Liu, Ho Kwang Mao

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Abstract

The stability field of the piezoelectric/ferroelectric phase of solid solution 0.47Pb(Yb 1/2Nb 1/2)O 3-0.53PbTiO 3 (PYN-PT) has been studied using in situ x-ray diffraction (XRD) and Raman spectroscopy techniques under high pressure and high temperature conditions to observe the evolution of features. PYN-PT remains in the piezoelectric tetragonal phase up to approximately 6.5 GPa at room temperature then transforms to a paraelectric cubic phase, which exhibits local disorder. The cubic phase is stable up to 50 GPa. Based on the high pressure and high temperature XRD results, we present a pressure-temperature phase diagram of PYN-PT which constraints the stability region of the ferroelectric phase.

Original languageEnglish (US)
Article number062904
JournalApplied Physics Letters
Volume101
Issue number6
DOIs
StatePublished - Aug 6 2012

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy (miscellaneous)

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    Kong, L., Wang, L., Zhang, S., Tschauner, O., Zhao, Y., Yang, W., Liu, H., & Mao, H. K. (2012). In situ structure characterization of Pb(Yb 1/2Nb 1/2)O 3-PbTiO 3 crystals under high pressure-temperature. Applied Physics Letters, 101(6), [062904]. https://doi.org/10.1063/1.4742165