Inclusion Polymerization within a Tris(2,3-naphthylenedioxy)cyclotriphosphazene Clathrate

Harry R. Allcock; Eric N. Silverberg; Gary K. Dudley; Shawn R. Pucher

doi:10.1021/ma00104a008

Inclusion Polymerization within a Tris(2,3-naphthylenedioxy)cyclotriphosphazene Clathrate

Harry R. Allcock, Eric N. Silverberg, Gary K. Dudley, Shawn R. Pucher

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Abstract

The inclusion and ⁶⁰Co γ-ray initiated polymerization of olefinic and acrylic monomers within the 10 Å clathrate-tunnels formed by tris(2,3-naphthylenedioxy)cyclotriphosphazene is described. Methyl acrylate, butyl acrylate, hexyl acrylate, octyl acrylate,isoprene, dimethylbutadiene, acrylonitrile, and methacrylonitrile monomers were included by direct contact imbibition. The resultant polymers were characterized by ¹H and ¹³C NMR spectroscopy, and the molecular weights were estimated by gel permeation chromatography and solution viscometry. The results are explained in terms of the host/guest relationship and structure. Comparisons are made where appropriate to similar polymers synthesized previously within the 5 Å tunnel of tris(o-phenylenedioxy)cyclotriphosphazene.

Original language	English (US)
Pages (from-to)	7550-7555
Number of pages	6
Journal	Macromolecules
Volume	27
Issue number	26
DOIs	https://doi.org/10.1021/ma00104a008
State	Published - Dec 1 1994

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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title = "Inclusion Polymerization within a Tris(2,3-naphthylenedioxy)cyclotriphosphazene Clathrate",

abstract = "The inclusion and 60Co γ-ray initiated polymerization of olefinic and acrylic monomers within the 10 {\AA} clathrate-tunnels formed by tris(2,3-naphthylenedioxy)cyclotriphosphazene is described. Methyl acrylate, butyl acrylate, hexyl acrylate, octyl acrylate,isoprene, dimethylbutadiene, acrylonitrile, and methacrylonitrile monomers were included by direct contact imbibition. The resultant polymers were characterized by 1H and 13C NMR spectroscopy, and the molecular weights were estimated by gel permeation chromatography and solution viscometry. The results are explained in terms of the host/guest relationship and structure. Comparisons are made where appropriate to similar polymers synthesized previously within the 5 {\AA} tunnel of tris(o-phenylenedioxy)cyclotriphosphazene.",

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T1 - Inclusion Polymerization within a Tris(2,3-naphthylenedioxy)cyclotriphosphazene Clathrate

AU - Allcock, Harry R.

AU - Silverberg, Eric N.

AU - Dudley, Gary K.

AU - Pucher, Shawn R.

PY - 1994/12/1

Y1 - 1994/12/1

N2 - The inclusion and 60Co γ-ray initiated polymerization of olefinic and acrylic monomers within the 10 Å clathrate-tunnels formed by tris(2,3-naphthylenedioxy)cyclotriphosphazene is described. Methyl acrylate, butyl acrylate, hexyl acrylate, octyl acrylate,isoprene, dimethylbutadiene, acrylonitrile, and methacrylonitrile monomers were included by direct contact imbibition. The resultant polymers were characterized by 1H and 13C NMR spectroscopy, and the molecular weights were estimated by gel permeation chromatography and solution viscometry. The results are explained in terms of the host/guest relationship and structure. Comparisons are made where appropriate to similar polymers synthesized previously within the 5 Å tunnel of tris(o-phenylenedioxy)cyclotriphosphazene.

AB - The inclusion and 60Co γ-ray initiated polymerization of olefinic and acrylic monomers within the 10 Å clathrate-tunnels formed by tris(2,3-naphthylenedioxy)cyclotriphosphazene is described. Methyl acrylate, butyl acrylate, hexyl acrylate, octyl acrylate,isoprene, dimethylbutadiene, acrylonitrile, and methacrylonitrile monomers were included by direct contact imbibition. The resultant polymers were characterized by 1H and 13C NMR spectroscopy, and the molecular weights were estimated by gel permeation chromatography and solution viscometry. The results are explained in terms of the host/guest relationship and structure. Comparisons are made where appropriate to similar polymers synthesized previously within the 5 Å tunnel of tris(o-phenylenedioxy)cyclotriphosphazene.

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Inclusion Polymerization within a Tris(2,3-naphthylenedioxy)cyclotriphosphazene Clathrate

Abstract

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