Inclusion Polymerization within a Tris(2,3-naphthylenedioxy)cyclotriphosphazene Clathrate

Harry R. Allcock, Eric N. Silverberg, Gary K. Dudley, Shawn R. Pucher

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

The inclusion and 60Co γ-ray initiated polymerization of olefinic and acrylic monomers within the 10 Å clathrate-tunnels formed by tris(2,3-naphthylenedioxy)cyclotriphosphazene is described. Methyl acrylate, butyl acrylate, hexyl acrylate, octyl acrylate,isoprene, dimethylbutadiene, acrylonitrile, and methacrylonitrile monomers were included by direct contact imbibition. The resultant polymers were characterized by 1H and 13C NMR spectroscopy, and the molecular weights were estimated by gel permeation chromatography and solution viscometry. The results are explained in terms of the host/guest relationship and structure. Comparisons are made where appropriate to similar polymers synthesized previously within the 5 Å tunnel of tris(o-phenylenedioxy)cyclotriphosphazene.

Original languageEnglish (US)
Pages (from-to)7550-7555
Number of pages6
JournalMacromolecules
Volume27
Issue number26
DOIs
StatePublished - Dec 1 1994

Fingerprint

Tunnels
Polymers
Polymerization
Acrylonitrile
Acrylic monomers
Isoprene
Viscosity measurement
Gel permeation chromatography
Nuclear magnetic resonance spectroscopy
Monomers
Molecular weight
hexyl acrylate
methyl acrylate
tris(o-phenylenedioxy)cyclotriphosphazene
acrylic acid
methacrylonitrile
isoprene
n-butyl acrylate

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Allcock, Harry R. ; Silverberg, Eric N. ; Dudley, Gary K. ; Pucher, Shawn R. / Inclusion Polymerization within a Tris(2,3-naphthylenedioxy)cyclotriphosphazene Clathrate. In: Macromolecules. 1994 ; Vol. 27, No. 26. pp. 7550-7555.
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Inclusion Polymerization within a Tris(2,3-naphthylenedioxy)cyclotriphosphazene Clathrate. / Allcock, Harry R.; Silverberg, Eric N.; Dudley, Gary K.; Pucher, Shawn R.

In: Macromolecules, Vol. 27, No. 26, 01.12.1994, p. 7550-7555.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Inclusion Polymerization within a Tris(2,3-naphthylenedioxy)cyclotriphosphazene Clathrate

AU - Allcock, Harry R.

AU - Silverberg, Eric N.

AU - Dudley, Gary K.

AU - Pucher, Shawn R.

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N2 - The inclusion and 60Co γ-ray initiated polymerization of olefinic and acrylic monomers within the 10 Å clathrate-tunnels formed by tris(2,3-naphthylenedioxy)cyclotriphosphazene is described. Methyl acrylate, butyl acrylate, hexyl acrylate, octyl acrylate,isoprene, dimethylbutadiene, acrylonitrile, and methacrylonitrile monomers were included by direct contact imbibition. The resultant polymers were characterized by 1H and 13C NMR spectroscopy, and the molecular weights were estimated by gel permeation chromatography and solution viscometry. The results are explained in terms of the host/guest relationship and structure. Comparisons are made where appropriate to similar polymers synthesized previously within the 5 Å tunnel of tris(o-phenylenedioxy)cyclotriphosphazene.

AB - The inclusion and 60Co γ-ray initiated polymerization of olefinic and acrylic monomers within the 10 Å clathrate-tunnels formed by tris(2,3-naphthylenedioxy)cyclotriphosphazene is described. Methyl acrylate, butyl acrylate, hexyl acrylate, octyl acrylate,isoprene, dimethylbutadiene, acrylonitrile, and methacrylonitrile monomers were included by direct contact imbibition. The resultant polymers were characterized by 1H and 13C NMR spectroscopy, and the molecular weights were estimated by gel permeation chromatography and solution viscometry. The results are explained in terms of the host/guest relationship and structure. Comparisons are made where appropriate to similar polymers synthesized previously within the 5 Å tunnel of tris(o-phenylenedioxy)cyclotriphosphazene.

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