Influence of crystallization conditions on the microstructure and electromechanical properties of poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) terpolymers

Rob J. Klein, J. Runt, Q. M. Zhang

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Abstract

The crystallization process and its influence on the microstructures and in turn the ferroelectric and electromechanical properties of poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) (P(VDF-TrFE-CFE)) terpolymer were investigated. It was found that, in addition to the crystallites formed at the isothermal crystallization temperature Tx, further crystallites form during the rapid cooling from Tx to room temperature. The proportion of lower melting crystallites increases with Tx, and for Tx = 142°C, this proportion is more than 90%. The experimental results show that the lower melting crystallites have a higher fraction of the all-trans conformation (and thus more polar-phase component) than the crystallites formed at Tx. As a result, the higher Tx samples show an increased polarization hysteresis and reduced electric field induced strain response. For example, the strain is reduced from -5.9 to -4.2% as Tx is increased from 112 to 142°C. In addition, the experimental results in combination with other reported results indicate that CFE units are included in the crystalline lattice. Consequently, the influence of CFE on the ferroelectric behavior of the polymer is through the defects induced in the crystal lattice.

Original languageEnglish (US)
Pages (from-to)7220-7226
Number of pages7
JournalMacromolecules
Volume36
Issue number19
DOIs
StatePublished - Sep 23 2003

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All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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