Influence of dispersion states on the performance of polymer-based nanocomposites

Payam Khodaparast, Zoubeida Ounaies

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Although nanoparticle-modified polymers have tremendous promise in many applications, particularly dielectric energy storage, true nanoscale dispersion is extremely difficult to achieve. In this paper, we carefully engineer various dispersion states of titania nanoparticles in polyvinylidene fluoride and analyze their impact on dielectric behavior and energy storage ability. In particular, we compare nanocomposites prepared using commercially available nanoparticles to those we prepared using in situ and ex situ synthesis of nanoparticles. SEM and TEM studies showed that the in situ case leads to the best dispersion. Interestingly, dielectric permittivity was most influenced by dispersion state where the in situ case showed a higher increase, however, dielectric breakdown and energy storage density were less affected by dispersion and more affected by procedure that minimized residues and impurities. The in situ technique, in particular, showed nanoscale dispersion, low dielectric loss and higher energy storage density. In terms of mechanical behavior, all three cases showed a similar performance in the rubbery region, whereas the impact of dispersion was more pronounced in the glassy region. In fact, the trend was opposite to the dielectric permittivity where nanoscale dispersion resulted in a lower storage modulus likely due to the lower effective mechanical load transfer going to the nanoscale. The results of our study shed some light on the role of dispersion quality and processing techniques in affecting the final dielectric, mechanical and breakdown behavior of TiO2-based polymer nanocomposites.

Original languageEnglish (US)
Article number104004
JournalSmart Materials and Structures
Volume23
Issue number10
DOIs
StatePublished - Oct 1 2014

Fingerprint

Nanocomposites
nanocomposites
Polymers
polymers
energy storage
Energy storage
Nanoparticles
nanoparticles
Permittivity
breakdown
permittivity
vinylidene
Dielectric losses
Electric breakdown
dielectric loss
engineers
fluorides
titanium
Titanium
Elastic moduli

All Science Journal Classification (ASJC) codes

  • Signal Processing
  • Civil and Structural Engineering
  • Atomic and Molecular Physics, and Optics
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Electrical and Electronic Engineering

Cite this

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Influence of dispersion states on the performance of polymer-based nanocomposites. / Khodaparast, Payam; Ounaies, Zoubeida.

In: Smart Materials and Structures, Vol. 23, No. 10, 104004, 01.10.2014.

Research output: Contribution to journalArticle

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