Influence of polymer chain connectivity on local composition distribution in miscible polymer blends

D. Bedrov, W. Liu, Ralph H. Colby

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Molecular dynamics simulations using a generic bead-necklace model were utilized to investigate the concentration distribution of local environments in model polymer blends. The distribution of effective composition around polymer segments was investigated for different blend scenarios and bulk concentrations. Inter- and intra-molecular contributions to the effective composition are analyzed. The analysis indicates that chain connectivity has significant and non-trivial effects on the distribution of effective composition around a polymer segment. The results of this work are compared with assumptions of several theoretical models that have been commonly used to describe structural and dynamical correlations in miscible polymer blends.

Original languageEnglish (US)
Pages (from-to)3979-3989
Number of pages11
JournalPhilosophical Magazine
Volume88
Issue number33-35
DOIs
StatePublished - Nov 1 2008

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polymer blends
polymers
beads
molecular dynamics
simulation

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics

Cite this

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Influence of polymer chain connectivity on local composition distribution in miscible polymer blends. / Bedrov, D.; Liu, W.; Colby, Ralph H.

In: Philosophical Magazine, Vol. 88, No. 33-35, 01.11.2008, p. 3979-3989.

Research output: Contribution to journalArticle

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