Influence of shape on the optical properties of hematite aerosol

Daniel P. Veghte, Justin E. Moore, Lasse Jensen, Miriam Arak Freedman

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Mineral dust particles are the second highest emitted aerosol type by mass. Due to changes in particle size, composition, and shape that are caused by physical processes and reactive chemistry, optical properties vary during transport, contributing uncertainty in the calculation of radiative forcing. Hematite is the major absorbing species of mineral dust. In this study, we analyzed the extinction cross sections of nigrosin and hematite particles using cavity ring-down aerosol extinction spectroscopy (CRD-AES) and have measured particle shape and size distributions using transmission electron microscopy. Nigrosin was also used in this study as a spherical standard for absorbing particles. The size-selected nigrosin particles have a narrow size distribution, with extinction cross sections that are described by Mie theory. In contrast, the size distribution of size-selected hematite particles is more polydisperse. The extinction cross sections were modeled using Mie theory and the discrete dipole approximation (DDA). The DDA was used to model more complex shapes that account for the surface roughness and particle geometry. Of the four models used, Mie theory was the simplest to implement, but had significant error with a 26.1% difference from the CRD-AES results. By increasing the complexity of the models using the DDA, we determined that spheroids had a 14.7% difference, roughened spheres a 12.8% difference, and roughened spheroids a 11.2% difference from the experimental results. Using additional parameters that account for particle shape is necessary to model the optical properties of hematite particles and leads to improved extinction cross sections for modeling aerosol optical properties.

Original languageEnglish (US)
Pages (from-to)7025-7039
Number of pages15
JournalJournal of Geophysical Research
Volume120
Issue number14
DOIs
StatePublished - Jan 1 2015

Fingerprint

optical properties
hematite
aerosols
Aerosols
optical property
Optical properties
aerosol
extinction
Minerals
Dust
Mie theory
Spectroscopy
cross section
Mie scattering
Particles (particulate matter)
cross sections
spheroids
dust
dipoles
spectroscopy

All Science Journal Classification (ASJC) codes

  • Geophysics
  • Forestry
  • Oceanography
  • Aquatic Science
  • Ecology
  • Water Science and Technology
  • Soil Science
  • Geochemistry and Petrology
  • Earth-Surface Processes
  • Atmospheric Science
  • Earth and Planetary Sciences (miscellaneous)
  • Space and Planetary Science
  • Palaeontology

Cite this

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abstract = "Mineral dust particles are the second highest emitted aerosol type by mass. Due to changes in particle size, composition, and shape that are caused by physical processes and reactive chemistry, optical properties vary during transport, contributing uncertainty in the calculation of radiative forcing. Hematite is the major absorbing species of mineral dust. In this study, we analyzed the extinction cross sections of nigrosin and hematite particles using cavity ring-down aerosol extinction spectroscopy (CRD-AES) and have measured particle shape and size distributions using transmission electron microscopy. Nigrosin was also used in this study as a spherical standard for absorbing particles. The size-selected nigrosin particles have a narrow size distribution, with extinction cross sections that are described by Mie theory. In contrast, the size distribution of size-selected hematite particles is more polydisperse. The extinction cross sections were modeled using Mie theory and the discrete dipole approximation (DDA). The DDA was used to model more complex shapes that account for the surface roughness and particle geometry. Of the four models used, Mie theory was the simplest to implement, but had significant error with a 26.1{\%} difference from the CRD-AES results. By increasing the complexity of the models using the DDA, we determined that spheroids had a 14.7{\%} difference, roughened spheres a 12.8{\%} difference, and roughened spheroids a 11.2{\%} difference from the experimental results. Using additional parameters that account for particle shape is necessary to model the optical properties of hematite particles and leads to improved extinction cross sections for modeling aerosol optical properties.",
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Influence of shape on the optical properties of hematite aerosol. / Veghte, Daniel P.; Moore, Justin E.; Jensen, Lasse; Freedman, Miriam Arak.

In: Journal of Geophysical Research, Vol. 120, No. 14, 01.01.2015, p. 7025-7039.

Research output: Contribution to journalArticle

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