Interactions and exchange of CO2 and H2O in coals: An investigation by low-field NMR relaxation

Xiaoxiao Sun, Yanbin Yao, Dameng Liu, Derek Elsworth, Zhejun Pan

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The mechanisms by which CO2 and water interact in coal remain unclear and these are key questions for understanding ECBM processes and defining the long-term behaviour of injected CO2. In our experiments, we injected helium/CO2 to displace water in eight water-saturated samples. We used low-field NMR relaxation to investigate CO2 and water interactions in these coals across a variety of time-scales. The injection of helium did not change the T2 spectra of the coals. In contrast, the T2 spectra peaks of micro-capillary water gradually decreased and those of macro-capillary and bulk water increased with time after the injection of CO2. We assume that the CO2 diffuses through and/or dissolves into the capillary water to access the coal matrix interior, which promotes desorption of water molecules from the surfaces of coal micropores and mesopores. The replaced water mass is mainly related to the Langmuir adsorption volume of CO2 and increases as the CO2 adsorption capacity increases. Other factors, such as mineral composition, temperature and pressure, also influence the effective exchange between water and CO2. Finally, we built a quantified model to evaluate the efficiency of water replacement by CO2 injection with respect to temperature and pressure.

Original languageEnglish (US)
Article number19919
JournalScientific reports
Volume6
DOIs
StatePublished - Jan 28 2016

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nuclear magnetic resonance
coal
water
helium
adsorption
water exchange
water mass
desorption
replacement
temperature
timescale
matrix
mineral

All Science Journal Classification (ASJC) codes

  • General

Cite this

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abstract = "The mechanisms by which CO2 and water interact in coal remain unclear and these are key questions for understanding ECBM processes and defining the long-term behaviour of injected CO2. In our experiments, we injected helium/CO2 to displace water in eight water-saturated samples. We used low-field NMR relaxation to investigate CO2 and water interactions in these coals across a variety of time-scales. The injection of helium did not change the T2 spectra of the coals. In contrast, the T2 spectra peaks of micro-capillary water gradually decreased and those of macro-capillary and bulk water increased with time after the injection of CO2. We assume that the CO2 diffuses through and/or dissolves into the capillary water to access the coal matrix interior, which promotes desorption of water molecules from the surfaces of coal micropores and mesopores. The replaced water mass is mainly related to the Langmuir adsorption volume of CO2 and increases as the CO2 adsorption capacity increases. Other factors, such as mineral composition, temperature and pressure, also influence the effective exchange between water and CO2. Finally, we built a quantified model to evaluate the efficiency of water replacement by CO2 injection with respect to temperature and pressure.",
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Interactions and exchange of CO2 and H2O in coals : An investigation by low-field NMR relaxation. / Sun, Xiaoxiao; Yao, Yanbin; Liu, Dameng; Elsworth, Derek; Pan, Zhejun.

In: Scientific reports, Vol. 6, 19919, 28.01.2016.

Research output: Contribution to journalArticle

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