Interactions of Nitrosoalkanes/arenes, Nitrosamines, Nitrosothiols, and Alkyl Nitrites with Metals

Nan Xu, George B. Richter-Addo

Research output: Chapter in Book/Report/Conference proceedingChapter

9 Scopus citations

Abstract

This chapter focuses attention on the interactions of four types of organo-NOx (x= 1) compounds with metals. It describes the chemistry of C-nitroso compounds, N-nitroso compounds, S-nitroso compounds, and O-nitroso compounds. Nitrosoalkanes and nitrosoarenes frequently serve as ligands to metal centers, and in many cases simple adduct formation between the pre-formed C-nitroso compounds and metal centers occur with or without the displacement of an existing ligand on the metal. The chapter presents the synthetic routes to metal-nitrosoalkane and metal-nitrosoarene compounds and the binding modes of the C-nitroso ligands that have been established crystallographically. It examines the fundamental coordination chemistry of these organonitroso compounds with metal centers that form the basis for their observed chemical and biochemical reactivity. Adsorption of alkyl nitrites on metal surfaces frequently results in the generation of alkoxy radicals and NO, and can lead to follow-up reactions with other substrates.

Original languageEnglish (US)
Title of host publicationProgress in Inorganic Chemistry
PublisherWiley-Blackwell
Pages381-446
Number of pages66
Volume59
ISBN (Electronic)9781118869994
ISBN (Print)9781118870167
DOIs
StatePublished - Jul 28 2014

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Engineering(all)
  • Materials Science(all)
  • Biochemistry, Genetics and Molecular Biology(all)

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