Investigation of fluorinated amides for solid-electrolyte interphase stabilization in Li-O2 batteries using amide-based electrolytes

Vyacheslav S. Bryantsev, Vincent Giordani, Wesley Walker, Jasim Uddin, Ilkeun Lee, Adri Van Duin, Gregory V. Chase, Dan Addison

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Solvent and electrode stability is critical for the successful development of the rechargeable, organic electrolyte Li-O2 (air) battery. Straight-chain alkyl amides, such as N,N-dimethylacetamide (DMA), show superior stability at the O2 cathode compared to organic carbonates and glymes, but these solvents do not form a stable solid-electrolyte interphase (SEI) to prevent a sustained reaction with Li metal. In this work, we use electrochemical impedance spectroscopy and cycling tests on a symmetric Li/electrolyte/Li cell to determine the ability of several fluorinated amide solvents to stabilize the lithium/electrolyte interface. The LiTFSI/N,N-dimethyltrifluoroacetamide (DMTFA) system shows the smallest interfacial impedance and the lowest polarization for Li dissolution and deposition. We present quantum chemical calculations indicating that α-fluorinated alkyl amides are reduced on Li to form insoluble LiF with no or little activation energy. XPS analysis confirms the presence of LiF in the SEI on Li metal exposed to DMTFA, which is likely to play an important role in stabilizing the lithium/electrolyte interface. The improved stability of a metallic Li anode in a rechargeable Li-O2 battery with LiTFSI/DMA electrolyte is demonstrated using 2% DMTFA as the SEI-stabilizing additive.

Original languageEnglish (US)
Pages (from-to)11977-11988
Number of pages12
JournalJournal of Physical Chemistry C
Volume117
Issue number23
DOIs
StatePublished - Jun 13 2013

Fingerprint

Solid electrolytes
solid electrolytes
Amides
amides
Electrolytes
electric batteries
Stabilization
stabilization
electrolytes
Lithium
lithium
Metals
impedance
Carbonates
Electrochemical impedance spectroscopy
metals
carbonates
Anodes
dissolving
Dissolution

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Bryantsev, Vyacheslav S. ; Giordani, Vincent ; Walker, Wesley ; Uddin, Jasim ; Lee, Ilkeun ; Van Duin, Adri ; Chase, Gregory V. ; Addison, Dan. / Investigation of fluorinated amides for solid-electrolyte interphase stabilization in Li-O2 batteries using amide-based electrolytes. In: Journal of Physical Chemistry C. 2013 ; Vol. 117, No. 23. pp. 11977-11988.
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Investigation of fluorinated amides for solid-electrolyte interphase stabilization in Li-O2 batteries using amide-based electrolytes. / Bryantsev, Vyacheslav S.; Giordani, Vincent; Walker, Wesley; Uddin, Jasim; Lee, Ilkeun; Van Duin, Adri; Chase, Gregory V.; Addison, Dan.

In: Journal of Physical Chemistry C, Vol. 117, No. 23, 13.06.2013, p. 11977-11988.

Research output: Contribution to journalArticle

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AU - Bryantsev, Vyacheslav S.

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