Investigation of intricate, amphiphilic crosslinked hyperbranched fluoropolymers as anti-icing coatings for extreme environments

Jennifer S. Zigmond; Kevin A. Pollack; Sarah Smedley; Jeffery E. Raymond; Lauren A. Link; Adriana Pavía-Sanders; Michael A. Hickner; Karen L. Wooley

doi:10.1002/pola.27800

Investigation of intricate, amphiphilic crosslinked hyperbranched fluoropolymers as anti-icing coatings for extreme environments

Jennifer S. Zigmond, Kevin A. Pollack, Sarah Smedley, Jeffery E. Raymond, Lauren A. Link, Adriana Pavía-Sanders, Michael A. Hickner, Karen L. Wooley

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

An array of films composed of a third-generation hyperbranched fluoropolymer crosslinked with poly(ethylene glycol) is generated and tested as an anti-icing coating. Through variation of the hydrophilic:hydrophobic component ratios and drop-casting solvent, significant reductions in the water melting transition temperatures (-5 and -27 C for free and bound water, respectively) are achieved. The novel application of this system displays the expansion and diversity of a well-established coating that demonstrates unique water confinement and sequestration behaviors with the ability to reorganize at the surface.

Original language	English (US)
Pages (from-to)	238-244
Number of pages	7
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	54
Issue number	2
DOIs	https://doi.org/10.1002/pola.27800
State	Published - Jan 15 2016

All Science Journal Classification (ASJC) codes

Polymers and Plastics
Organic Chemistry
Materials Chemistry

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10.1002/pola.27800

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Zigmond, Jennifer S. ; Pollack, Kevin A. ; Smedley, Sarah ; Raymond, Jeffery E. ; Link, Lauren A. ; Pavía-Sanders, Adriana ; Hickner, Michael A. ; Wooley, Karen L. / Investigation of intricate, amphiphilic crosslinked hyperbranched fluoropolymers as anti-icing coatings for extreme environments. In: Journal of Polymer Science, Part A: Polymer Chemistry. 2016 ; Vol. 54, No. 2. pp. 238-244.

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abstract = "An array of films composed of a third-generation hyperbranched fluoropolymer crosslinked with poly(ethylene glycol) is generated and tested as an anti-icing coating. Through variation of the hydrophilic:hydrophobic component ratios and drop-casting solvent, significant reductions in the water melting transition temperatures (-5 and -27 C for free and bound water, respectively) are achieved. The novel application of this system displays the expansion and diversity of a well-established coating that demonstrates unique water confinement and sequestration behaviors with the ability to reorganize at the surface.",

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Investigation of intricate, amphiphilic crosslinked hyperbranched fluoropolymers as anti-icing coatings for extreme environments. / Zigmond, Jennifer S.; Pollack, Kevin A.; Smedley, Sarah; Raymond, Jeffery E.; Link, Lauren A.; Pavía-Sanders, Adriana; Hickner, Michael A.; Wooley, Karen L.

In: Journal of Polymer Science, Part A: Polymer Chemistry, Vol. 54, No. 2, 15.01.2016, p. 238-244.

Research output: Contribution to journal › Article › peer-review

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