Investigation of morphotropic phase boundaries in PIN–PSN–PT relaxor ferroelectric ternary systems with high Tr-t and Tc phase transition temperatures

Dabin Lin, Shujun Zhang, Edward Gorzkowski, Shun Zhou, Weiguo Liu, Fei Li

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

New morphotropic phase boundary (MPB) compositions with relatively high Tcs were projected in Pb(In1/2Nb1/2)O3–Pb(Sc1/2Nb1/2)O3–PbTiO3 (PIN–PSN–PT) solid solution based on the perovskite tolerance factor, and were experimentally confirmed. The phase structure, dielectric, pyroelectric, piezoelectric and ferroelectric properties of PIN–PSN–PT ceramics were investigated. The rhombohedral–tetragonal phase transition temperatures Tr-t on the order of 189–210 °C, Curie temperatures Tc on the order of 274–285 °C and piezoelectric coefficients d33 in the range of 310–360 pC/N, were achieved in xPIN– (1 − x)PSN–0.37PT (x = 0.15–0.23) ceramics, demonstrating a promising relaxor–PbTiO3 system with high phase transition temperatures. In addition, the maps of Tc, Tr-t, d33 and εr with respect to composition were established, based on which, a clear direction for composition screening in future crystal growth of the PIN–PSN–PT system was given.

Original languageEnglish (US)
Pages (from-to)2813-2823
Number of pages11
JournalJournal of the European Ceramic Society
Volume37
Issue number8
DOIs
StatePublished - Jul 1 2017

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Phase boundaries
Ternary systems
Superconducting transition temperature
Ferroelectric materials
Phase transitions
Chemical analysis
Phase structure
Curie temperature
Crystallization
Crystal growth
Perovskite
Solid solutions
Screening

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

Cite this

Lin, Dabin ; Zhang, Shujun ; Gorzkowski, Edward ; Zhou, Shun ; Liu, Weiguo ; Li, Fei. / Investigation of morphotropic phase boundaries in PIN–PSN–PT relaxor ferroelectric ternary systems with high Tr-t and Tc phase transition temperatures. In: Journal of the European Ceramic Society. 2017 ; Vol. 37, No. 8. pp. 2813-2823.
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abstract = "New morphotropic phase boundary (MPB) compositions with relatively high Tcs were projected in Pb(In1/2Nb1/2)O3–Pb(Sc1/2Nb1/2)O3–PbTiO3 (PIN–PSN–PT) solid solution based on the perovskite tolerance factor, and were experimentally confirmed. The phase structure, dielectric, pyroelectric, piezoelectric and ferroelectric properties of PIN–PSN–PT ceramics were investigated. The rhombohedral–tetragonal phase transition temperatures Tr-t on the order of 189–210 °C, Curie temperatures Tc on the order of 274–285 °C and piezoelectric coefficients d33 in the range of 310–360 pC/N, were achieved in xPIN– (1 − x)PSN–0.37PT (x = 0.15–0.23) ceramics, demonstrating a promising relaxor–PbTiO3 system with high phase transition temperatures. In addition, the maps of Tc, Tr-t, d33 and εr with respect to composition were established, based on which, a clear direction for composition screening in future crystal growth of the PIN–PSN–PT system was given.",
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Investigation of morphotropic phase boundaries in PIN–PSN–PT relaxor ferroelectric ternary systems with high Tr-t and Tc phase transition temperatures. / Lin, Dabin; Zhang, Shujun; Gorzkowski, Edward; Zhou, Shun; Liu, Weiguo; Li, Fei.

In: Journal of the European Ceramic Society, Vol. 37, No. 8, 01.07.2017, p. 2813-2823.

Research output: Contribution to journalArticle

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