Iridescence in metamorphic "rainbow" hematite

Xiayang Lin, Peter J. Heaney, Jeffrey E. Post

Research output: Contribution to journalArticle

Abstract

The authors investigated "rainbow" hematite from Minas Gerais, Brazil, using electron microscopy, atomic force microscopy, and synchrotron X-ray diffraction to determine the cause of its intense wide-angle iridescence. The study revealed that the interference is produced by a highly periodic microstructure consisting of spindle-shaped hematite nanocrystals containing minor Al and P impurities. The nanorods are 200-300 nm in length and 50-60 nm in width. They are arranged in three orientations at 120° angles with respect to each other and stacked layer by layer to form the bulk crystal. The distances between adjacent parallel spindle-shaped particles within the same layer fall in the range of 280-400 nm, generating a diffraction grating for visible light. The organized substructure is apparent on all freshly fractured surfaces, suggesting that it represents more than an exterior surface coating. The authors propose that this periodic substructure results from arrested crystal growth by the oriented aggregation of hematite nanorods.

Original languageEnglish (US)
Pages (from-to)28-39
Number of pages12
JournalGems and Gemology
Volume54
Issue number1
DOIs
StatePublished - Mar 1 2018

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hematite
rainbow
Nanorods
crystal
atomic force microscopy
Diffraction gratings
Crystallization
electron microscopy
Synchrotrons
Nanocrystals
diffraction
Electron microscopy
Atomic force microscopy
coating
microstructure
Agglomeration
X-ray diffraction
Impurities
X ray diffraction
Coatings

All Science Journal Classification (ASJC) codes

  • Geochemistry and Petrology

Cite this

Lin, Xiayang ; Heaney, Peter J. ; Post, Jeffrey E. / Iridescence in metamorphic "rainbow" hematite. In: Gems and Gemology. 2018 ; Vol. 54, No. 1. pp. 28-39.
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Iridescence in metamorphic "rainbow" hematite. / Lin, Xiayang; Heaney, Peter J.; Post, Jeffrey E.

In: Gems and Gemology, Vol. 54, No. 1, 01.03.2018, p. 28-39.

Research output: Contribution to journalArticle

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