Isothermal thermogravimetric analysis of soybean oil oxidation correlated to thin film micro-oxidation test methods

Mert Arca, Brajendra K. Sharma, Joseph Manuel Sr Perez, Kenneth M. Doll

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

An isothermal thermogravimetric analysis (TGA) method was used to generate a model capable of predicting the results of the Thin Film Micro-Oxidation (TFMO) test in a soybean oil system. Utilizing a series of pseudorate constants and "activation energies", weight loss data from the TGA method can predict oxidation, polymerization, evaporation, and the formation of high molecular weight deposits, normally observed in the TFMO test. These parameters can be used in simple computer simulations which can calculate the weight of each component of a lubricant as it decomposes. This allows evaluation of lubricants without the difficult to obtain TFMO equipment, instead utilizing equipment available in most laboratories.

Original languageEnglish (US)
Pages (from-to)3550-3555
Number of pages6
JournalIndustrial and Engineering Chemistry Research
Volume51
Issue number9
DOIs
StatePublished - Jun 14 2012

Fingerprint

Soybean oil
Soybean Oil
Thermogravimetric analysis
Thin films
Oxidation
Lubricants
Evaporation
Deposits
Activation energy
Molecular weight
Polymerization
Computer simulation

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

Arca, Mert ; Sharma, Brajendra K. ; Perez, Joseph Manuel Sr ; Doll, Kenneth M. / Isothermal thermogravimetric analysis of soybean oil oxidation correlated to thin film micro-oxidation test methods. In: Industrial and Engineering Chemistry Research. 2012 ; Vol. 51, No. 9. pp. 3550-3555.
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Isothermal thermogravimetric analysis of soybean oil oxidation correlated to thin film micro-oxidation test methods. / Arca, Mert; Sharma, Brajendra K.; Perez, Joseph Manuel Sr; Doll, Kenneth M.

In: Industrial and Engineering Chemistry Research, Vol. 51, No. 9, 14.06.2012, p. 3550-3555.

Research output: Contribution to journalArticle

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