Kinetic modeling of electro-Fenton reaction in aqueous solution

H. Liu, X. Z. Li, Yongjun Leng, C. Wang

    Research output: Contribution to journalArticle

    79 Citations (Scopus)

    Abstract

    To well describe the electro-Fenton (E-Fenton) reaction in aqueous solution, a new kinetic model was established according to the generally accepted mechanism of E-Fenton reaction. The model has special consideration on the rates of hydrogen peroxide (H2O2) generation and consumption in the reaction solution. The model also embraces three key operating factors affecting the organic degradation in the E-Fenton reaction, including current density, dissolved oxygen concentration and initial ferrous ion concentration. This analytical model was then validated by the experiments of phenol degradation in aqueous solution. The experiments demonstrated that the H2O2 gradually built up with time and eventually approached its maximum value in the reaction solution. The experiments also showed that phenol was degraded at a slow rate at the early stage of the reaction, a faster rate during the middle stage, and a slow rate again at the final stage. It was confirmed in all experiments that the curves of phenol degradation (concentration vs. time) appeared to be an inverted "S" shape. The experimental data were fitted using both the normal first-order model and our new model, respectively. The goodness of fittings demonstrated that the new model could better fit the experimental data than the first-order model appreciably, which indicates that this analytical model can better describe the kinetics of the E-Fenton reaction mathematically and also chemically.

    Original languageEnglish (US)
    Pages (from-to)1161-1167
    Number of pages7
    JournalWater Research
    Volume41
    Issue number5
    DOIs
    StatePublished - Mar 1 2007

    Fingerprint

    aqueous solution
    kinetics
    Kinetics
    modeling
    Phenols
    phenol
    Degradation
    Analytical models
    Experiments
    degradation
    experiment
    Dissolved oxygen
    Hydrogen peroxide
    Current density
    density current
    hydrogen peroxide
    dissolved oxygen
    Ions
    rate
    ion

    All Science Journal Classification (ASJC) codes

    • Ecological Modeling
    • Water Science and Technology
    • Waste Management and Disposal
    • Pollution

    Cite this

    Liu, H. ; Li, X. Z. ; Leng, Yongjun ; Wang, C. / Kinetic modeling of electro-Fenton reaction in aqueous solution. In: Water Research. 2007 ; Vol. 41, No. 5. pp. 1161-1167.
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    Kinetic modeling of electro-Fenton reaction in aqueous solution. / Liu, H.; Li, X. Z.; Leng, Yongjun; Wang, C.

    In: Water Research, Vol. 41, No. 5, 01.03.2007, p. 1161-1167.

    Research output: Contribution to journalArticle

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