Large kinetic asymmetry in the metal-insulator transition nucleated at localized and extended defects

W. Fan, J. Cao, J. Seidel, Y. Gu, J. W. Yim, C. Barrett, K. M. Yu, J. Ji, R. Ramesh, L. Q. Chen, J. Wu

Research output: Contribution to journalArticle

65 Citations (Scopus)

Abstract

Superheating and supercooling effects are characteristic kinetic processes in first-order phase transitions, and asymmetry between them is widely observed. In materials where electronic and structural degrees of freedom are coupled, a wide, asymmetric hysteresis may occur in the transition between electronic phases. Structural defects are known to seed heterogeneous nucleation of the phase transition, hence reduce the degree of superheating and supercooling. Here we show that in the metal-insulator transition of single-crystal VO 2, a large kinetic asymmetry arises from the distinct spatial extension and distribution of two basic types of crystal defects: point defects and twin walls. Nanometer-thick twin walls are constantly consumed but regenerated during the transition to the metal phase, serving as dynamical heterogeneous nucleation seeds and eliminating superheating. On the other hand, the transition back to the insulator phase relies on nucleation at point defects because twinning is structurally forbidden in the metal phase, leading to a large supercooling. By controlling the formation, location, and extinction of these defects, the kinetics of the phase transition might be externally modulated, offering possible routes toward unique memory and logic device technologies.

Original languageEnglish (US)
Article number235102
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume83
Issue number23
DOIs
StatePublished - Jun 2 2011

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Supercooling
Metal insulator transition
Nucleation
Phase transitions
asymmetry
insulators
Point defects
Defects
Kinetics
Seed
defects
kinetics
superheating
Metals
metals
supercooling
Logic devices
Crystal defects
Twinning
nucleation

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

Cite this

Fan, W. ; Cao, J. ; Seidel, J. ; Gu, Y. ; Yim, J. W. ; Barrett, C. ; Yu, K. M. ; Ji, J. ; Ramesh, R. ; Chen, L. Q. ; Wu, J. / Large kinetic asymmetry in the metal-insulator transition nucleated at localized and extended defects. In: Physical Review B - Condensed Matter and Materials Physics. 2011 ; Vol. 83, No. 23.
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Large kinetic asymmetry in the metal-insulator transition nucleated at localized and extended defects. / Fan, W.; Cao, J.; Seidel, J.; Gu, Y.; Yim, J. W.; Barrett, C.; Yu, K. M.; Ji, J.; Ramesh, R.; Chen, L. Q.; Wu, J.

In: Physical Review B - Condensed Matter and Materials Physics, Vol. 83, No. 23, 235102, 02.06.2011.

Research output: Contribution to journalArticle

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AU - Cao, J.

AU - Seidel, J.

AU - Gu, Y.

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AU - Barrett, C.

AU - Yu, K. M.

AU - Ji, J.

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AU - Wu, J.

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N2 - Superheating and supercooling effects are characteristic kinetic processes in first-order phase transitions, and asymmetry between them is widely observed. In materials where electronic and structural degrees of freedom are coupled, a wide, asymmetric hysteresis may occur in the transition between electronic phases. Structural defects are known to seed heterogeneous nucleation of the phase transition, hence reduce the degree of superheating and supercooling. Here we show that in the metal-insulator transition of single-crystal VO 2, a large kinetic asymmetry arises from the distinct spatial extension and distribution of two basic types of crystal defects: point defects and twin walls. Nanometer-thick twin walls are constantly consumed but regenerated during the transition to the metal phase, serving as dynamical heterogeneous nucleation seeds and eliminating superheating. On the other hand, the transition back to the insulator phase relies on nucleation at point defects because twinning is structurally forbidden in the metal phase, leading to a large supercooling. By controlling the formation, location, and extinction of these defects, the kinetics of the phase transition might be externally modulated, offering possible routes toward unique memory and logic device technologies.

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