Li-ion cell operation at low temperatures

Yan Ji, Yancheng Zhang, Chao-yang Wang

Research output: Contribution to journalArticle

200 Citations (Scopus)

Abstract

Substantially reduced energy and power capabilities of lithium-ion cell operating at low temperatures pose a technical barrier for market penetration of hybrid electric vehicles and pure electric vehicles. The present work delineates Li-ion cell behaviors at low temperatures by a combined experimental and modeling approach. An electrochemical-thermal coupled model, incorporating concentration- and temperature-dependent transport and kinetic properties, is applied and validated against 2.2Ah 18650 cylindrical cells over a wide range of temperatures (-20°C to 45°C) and discharge rates. Simulation and experimental results demonstrate the dramatic effects of cell self-heating upon electrochemical performance. A nonisothermal Ragone plot accounting for these important thermal effects is proposed for the first time for Li-ion cells and more generally for thermally coupled batteries. Detailed resistance analysis indicates that performance limits at -20°C depend on not only discharge rates but also thermal conditions. Optimization of cell design parameters and material properties is performed for 1 C rate discharge starting from -20°C, where the principal performance limitations are found to be Li+ diffusion in the electrolyte and solid-state Li diffusion in graphite particles, instead of charge-transfer kinetic or ohmic resistance.

Original languageEnglish (US)
JournalJournal of the Electrochemical Society
Volume160
Issue number4
DOIs
StatePublished - Apr 8 2013

Fingerprint

Ions
Temperature
Kinetics
Acoustic impedance
Graphite
Hybrid vehicles
Electric vehicles
Lithium
Thermal effects
Electrolytes
Charge transfer
Materials properties
Heating
Hot Temperature

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Cite this

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Li-ion cell operation at low temperatures. / Ji, Yan; Zhang, Yancheng; Wang, Chao-yang.

In: Journal of the Electrochemical Society, Vol. 160, No. 4, 08.04.2013.

Research output: Contribution to journalArticle

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AB - Substantially reduced energy and power capabilities of lithium-ion cell operating at low temperatures pose a technical barrier for market penetration of hybrid electric vehicles and pure electric vehicles. The present work delineates Li-ion cell behaviors at low temperatures by a combined experimental and modeling approach. An electrochemical-thermal coupled model, incorporating concentration- and temperature-dependent transport and kinetic properties, is applied and validated against 2.2Ah 18650 cylindrical cells over a wide range of temperatures (-20°C to 45°C) and discharge rates. Simulation and experimental results demonstrate the dramatic effects of cell self-heating upon electrochemical performance. A nonisothermal Ragone plot accounting for these important thermal effects is proposed for the first time for Li-ion cells and more generally for thermally coupled batteries. Detailed resistance analysis indicates that performance limits at -20°C depend on not only discharge rates but also thermal conditions. Optimization of cell design parameters and material properties is performed for 1 C rate discharge starting from -20°C, where the principal performance limitations are found to be Li+ diffusion in the electrolyte and solid-state Li diffusion in graphite particles, instead of charge-transfer kinetic or ohmic resistance.

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