TY - JOUR
T1 - Lignin/collagen hybrid biomaterials as binder substitute for specialty graphites and electrodes
AU - Zhao, Zilong
AU - Cannon, Fred S.
AU - Nieto-Delgado, Cesar
AU - Pena, Leidy
N1 - Funding Information:
The authors gratefully acknowledge the support from Priority Academic Program Development of Jiangsu Higher Education Institutions (No. 1105007001 ), Research Fund for Taihu Lake Pollution Control of Jiangsu Province (No. TH2012207 ), Research and Innovation Project for College Graduates of Jiangsu Province (No. CXLX110129 ), and U.S. Department of Agriculture grant USDA NIFA 2011-67009-20049 . We gratefully acknowledge the graphitization of samples, as coordinated by Thomas Kraus of SGL Group – The Carbon Company, Morganton, North Carolina.
Publisher Copyright:
© 2016 Elsevier Ltd
PY - 2016/11/1
Y1 - 2016/11/1
N2 - Sustainable biomaterial binders were developed from lignin and collagen to replace the conventional petroleum pitch and coal tar pitch binders that have been used when making specialty graphites and graphite electrodes. The team prepared lab-scale graphite electrodes by first creating green composites, by hot-pressing together the lignin, collagen, petroleum coke, and other additives, followed by carbonization and graphitization. Response Surface Methodology (RSM) experimental design was employed, based on Box-Behnken Design (BBD). This was employed to optimize the recipes and processing protocols for the green composite hot-pressing of 3.5 cm diameter × 19 cm long cylinder specimens. Relative to density, the apparent optimum conditions occurred with 13.0% lignin, 3.6% collagen, 27.4% petroleum coke fines, and the balance of petroleum coke particles plus some additives. The green hot-pressing protocol employed 30 MPa pressure at 400 °C for 2 h. Baking peaked at 800 °C, ramped up and down over 13 days. This baked product hosted an apparent density of 1.67 g/mL, and exhibited 6.2% puffing. Another baked product hosted 1.56 g/mL and 1.67% puffing. After the baked product was graphitized, we achieved an apparent density of 1.51 g/mL and resistance of 25–30 μΩm. These results approached the specifications for specialty graphites.
AB - Sustainable biomaterial binders were developed from lignin and collagen to replace the conventional petroleum pitch and coal tar pitch binders that have been used when making specialty graphites and graphite electrodes. The team prepared lab-scale graphite electrodes by first creating green composites, by hot-pressing together the lignin, collagen, petroleum coke, and other additives, followed by carbonization and graphitization. Response Surface Methodology (RSM) experimental design was employed, based on Box-Behnken Design (BBD). This was employed to optimize the recipes and processing protocols for the green composite hot-pressing of 3.5 cm diameter × 19 cm long cylinder specimens. Relative to density, the apparent optimum conditions occurred with 13.0% lignin, 3.6% collagen, 27.4% petroleum coke fines, and the balance of petroleum coke particles plus some additives. The green hot-pressing protocol employed 30 MPa pressure at 400 °C for 2 h. Baking peaked at 800 °C, ramped up and down over 13 days. This baked product hosted an apparent density of 1.67 g/mL, and exhibited 6.2% puffing. Another baked product hosted 1.56 g/mL and 1.67% puffing. After the baked product was graphitized, we achieved an apparent density of 1.51 g/mL and resistance of 25–30 μΩm. These results approached the specifications for specialty graphites.
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U2 - 10.1016/j.carbon.2016.07.026
DO - 10.1016/j.carbon.2016.07.026
M3 - Article
AN - SCOPUS:84978706315
VL - 108
SP - 303
EP - 317
JO - Carbon
JF - Carbon
SN - 0008-6223
ER -