Longitudinal cutting of pure and doped carbon nanotubes to form graphitic nanoribbons using metal clusters as nanoscalpels

Ana Laura Elias Arriaga, Andrés R. Botello-Méndez, David Meneses-Rodríguez, Viviana Jehová González, Daniel Ramírez-González, Lijie Ci, Emilio Muñoz-Sandoval, Pulickel M. Ajayan, Humberto Terrones, Mauricio Terrones Maldonado

Research output: Contribution to journalArticle

254 Citations (Scopus)

Abstract

We report the use of transition metal nanoparticles (Ni or Co) to longitudinally cut open multiwalled carbon nanotubes in order to create graphitic nanoribbons. The process consists of catalytic hydrogenation of carbon, in which the metal particles cut sp2 hybridized carbon atoms along nanotubes that results in the liberation of hydrocarbon species. Observations reveal the presence of unzipped nanotubes that were cut by the nanoparticles. We also report the presence of partially open carbon nanotubes, which have been predicted to have novel magnetoresistance properties. 1 The nanoribbons produced are typically 15-40 nm wide and 100-500 nm long. This method offers an alternative approach for making graphene nanoribbons, compared to the chemical methods reported recently in the literature.

Original languageEnglish (US)
Pages (from-to)366-372
Number of pages7
JournalNano Letters
Volume10
Issue number2
DOIs
StatePublished - Feb 10 2010

Fingerprint

Nanoribbons
Carbon Nanotubes
metal clusters
Carbon nanotubes
nanotubes
Metals
carbon nanotubes
nanoparticles
Nanotubes
carbon
metal particles
hydrogenation
graphene
Carbon
Multiwalled carbon nanotubes (MWCN)
hydrocarbons
Metal nanoparticles
transition metals
Magnetoresistance
Graphene

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering

Cite this

Elias Arriaga, Ana Laura ; Botello-Méndez, Andrés R. ; Meneses-Rodríguez, David ; González, Viviana Jehová ; Ramírez-González, Daniel ; Ci, Lijie ; Muñoz-Sandoval, Emilio ; Ajayan, Pulickel M. ; Terrones, Humberto ; Terrones Maldonado, Mauricio. / Longitudinal cutting of pure and doped carbon nanotubes to form graphitic nanoribbons using metal clusters as nanoscalpels. In: Nano Letters. 2010 ; Vol. 10, No. 2. pp. 366-372.
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Elias Arriaga, AL, Botello-Méndez, AR, Meneses-Rodríguez, D, González, VJ, Ramírez-González, D, Ci, L, Muñoz-Sandoval, E, Ajayan, PM, Terrones, H & Terrones Maldonado, M 2010, 'Longitudinal cutting of pure and doped carbon nanotubes to form graphitic nanoribbons using metal clusters as nanoscalpels', Nano Letters, vol. 10, no. 2, pp. 366-372. https://doi.org/10.1021/nl901631z

Longitudinal cutting of pure and doped carbon nanotubes to form graphitic nanoribbons using metal clusters as nanoscalpels. / Elias Arriaga, Ana Laura; Botello-Méndez, Andrés R.; Meneses-Rodríguez, David; González, Viviana Jehová; Ramírez-González, Daniel; Ci, Lijie; Muñoz-Sandoval, Emilio; Ajayan, Pulickel M.; Terrones, Humberto; Terrones Maldonado, Mauricio.

In: Nano Letters, Vol. 10, No. 2, 10.02.2010, p. 366-372.

Research output: Contribution to journalArticle

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Elias Arriaga AL, Botello-Méndez AR, Meneses-Rodríguez D, González VJ, Ramírez-González D, Ci L et al. Longitudinal cutting of pure and doped carbon nanotubes to form graphitic nanoribbons using metal clusters as nanoscalpels. Nano Letters. 2010 Feb 10;10(2):366-372. https://doi.org/10.1021/nl901631z