Magnetic color symmetry of lattice rotations in a diamagnetic material

S. Denev, A. Kumar, M. D. Biegalski, H. W. Jang, C. M. Folkman, A. Vasudevarao, Y. Han, I. M. Reaney, S. Trolier-Mckinstry, C. B. Eom, D. G. Schlom, V. Gopalan

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Oxygen octahedral rotations are the most common phase transitions in perovskite crystal structures. Here we show that the color symmetry of such pure elastic distortions is isomorphic to magnetic point groups, which allows their probing through distinguishing polar versus magnetic symmetry. We demonstrate this isomorphism using nonlinear optical probing of the octahedral rotational transition in a compressively strained SrTiO3 thin film that exhibits ferroelectric (4mm) and antiferrodistortive (4′mm′) phases evolving through independent phase transitions. The approach has broader applicability for probing materials with lattice rotations that can be mapped to color groups.

Original languageEnglish (US)
Article number257601
JournalPhysical Review Letters
Issue number25
Publication statusPublished - Jun 23 2008


All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

Cite this

Denev, S., Kumar, A., Biegalski, M. D., Jang, H. W., Folkman, C. M., Vasudevarao, A., ... Gopalan, V. (2008). Magnetic color symmetry of lattice rotations in a diamagnetic material. Physical Review Letters, 100(25), [257601].