Mechanochemical synthesis of complex zirconium phosphates

M. V. Chaikina, V. A. Sadykov, S. N. Pavlova, G. N. Zabolotnaya, R. I. Maximovskaya, V. V. Kriventsov, D. I. Kochubey, E. B. Burgina, R. Roy, D. K. Agrawal

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Abstract

Cation- and anion-substituted zirconium phosphates of XkZrm(PO4)n-yY composition, where X = Na+, La3+, NH4+, Y = F-, WO42-, 1/3 < k < 2, 2 < m < 4, 3 < n < 6 were synthesized by the procedure, including mechanical activation of the starting salts mixture followed by annealing at 300-900°C. The interaction between components was studied by XRD, EXAFS, FT-IR, [31P-MAS] NMR. The possibility of synthesizing nonstoichiometric compounds is demonstrated and prospects for application of the mechanochemical method for synthesis of complex zirconium phosphates are outlined.

Original languageEnglish (US)
Pages (from-to)279-286
Number of pages8
JournalJournal of Materials Synthesis and Processing
Volume8
Issue number5-6
DOIs
StatePublished - Nov 1 2000

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

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    Chaikina, M. V., Sadykov, V. A., Pavlova, S. N., Zabolotnaya, G. N., Maximovskaya, R. I., Kriventsov, V. V., Kochubey, D. I., Burgina, E. B., Roy, R., & Agrawal, D. K. (2000). Mechanochemical synthesis of complex zirconium phosphates. Journal of Materials Synthesis and Processing, 8(5-6), 279-286. https://doi.org/10.1023/A:1011334125802