Mesoporous crystalline metal oxide as anode materials for lithium ion batteries

Donghai Wang, Vilayanur Viswanathan, Jun Liu, Zimin Nie

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A novel solution growth of metal oxide nanocrystals within an organized surfactant matrix into mesoporous three-dimensional nanostructured frameworks with tunable mesoporosity was developed. Mesoporous crystalline transition metal oxide including CeO2, SnO2, TiO2, and composite oxide TiO2/SnO2 was synthesized. Nanostructured TiO2 has attracted much attention in Li insertion because it is not only a low voltage insertion host for Li, but also a fast Li insertion/extraction host. These characteristics render it a potential anode material for high-power lithium-ion batteries. The synthesized mesoporous crystalline TiO2 were tested as anode materials for their cycling ability and stability. The mesoporous TiO2 was able to reversibly accommodate Li up to Li0.5TiO2 (168 mA-hr/g) at 1-3 v vs. Li+/Li with excellent capacity retention and high rate capability on cycling. Other mesoporous crystalline metal oxide including composite TiO2/SnO2 was studied in terms of capacities and stability as anode materials. This is an abstract of a paper presented at the AIChE Annual Meeting (Salt Lake, UT 11/4-9/2007).

Original languageEnglish (US)
Title of host publication2007 AIChE Annual Meeting
StatePublished - 2007
Event2007 AIChE Annual Meeting - Salt Lake City, UT, United States
Duration: Nov 4 2007Nov 9 2007

Other

Other2007 AIChE Annual Meeting
CountryUnited States
CitySalt Lake City, UT
Period11/4/0711/9/07

Fingerprint

Lithium
Oxides
Anodes
Electrodes
Metals
Ions
Crystalline materials
Metal Nanoparticles
Composite materials
Lakes
Surface-Active Agents
Nanocrystals
Transition metals
Surface active agents
Salts
Lithium-ion batteries
Electric potential
Growth

All Science Journal Classification (ASJC) codes

  • Biotechnology
  • Chemical Engineering(all)
  • Bioengineering
  • Safety, Risk, Reliability and Quality

Cite this

Wang, D., Viswanathan, V., Liu, J., & Nie, Z. (2007). Mesoporous crystalline metal oxide as anode materials for lithium ion batteries. In 2007 AIChE Annual Meeting
Wang, Donghai ; Viswanathan, Vilayanur ; Liu, Jun ; Nie, Zimin. / Mesoporous crystalline metal oxide as anode materials for lithium ion batteries. 2007 AIChE Annual Meeting. 2007.
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Wang, D, Viswanathan, V, Liu, J & Nie, Z 2007, Mesoporous crystalline metal oxide as anode materials for lithium ion batteries. in 2007 AIChE Annual Meeting. 2007 AIChE Annual Meeting, Salt Lake City, UT, United States, 11/4/07.

Mesoporous crystalline metal oxide as anode materials for lithium ion batteries. / Wang, Donghai; Viswanathan, Vilayanur; Liu, Jun; Nie, Zimin.

2007 AIChE Annual Meeting. 2007.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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T1 - Mesoporous crystalline metal oxide as anode materials for lithium ion batteries

AU - Wang, Donghai

AU - Viswanathan, Vilayanur

AU - Liu, Jun

AU - Nie, Zimin

PY - 2007

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N2 - A novel solution growth of metal oxide nanocrystals within an organized surfactant matrix into mesoporous three-dimensional nanostructured frameworks with tunable mesoporosity was developed. Mesoporous crystalline transition metal oxide including CeO2, SnO2, TiO2, and composite oxide TiO2/SnO2 was synthesized. Nanostructured TiO2 has attracted much attention in Li insertion because it is not only a low voltage insertion host for Li, but also a fast Li insertion/extraction host. These characteristics render it a potential anode material for high-power lithium-ion batteries. The synthesized mesoporous crystalline TiO2 were tested as anode materials for their cycling ability and stability. The mesoporous TiO2 was able to reversibly accommodate Li up to Li0.5TiO2 (168 mA-hr/g) at 1-3 v vs. Li+/Li with excellent capacity retention and high rate capability on cycling. Other mesoporous crystalline metal oxide including composite TiO2/SnO2 was studied in terms of capacities and stability as anode materials. This is an abstract of a paper presented at the AIChE Annual Meeting (Salt Lake, UT 11/4-9/2007).

AB - A novel solution growth of metal oxide nanocrystals within an organized surfactant matrix into mesoporous three-dimensional nanostructured frameworks with tunable mesoporosity was developed. Mesoporous crystalline transition metal oxide including CeO2, SnO2, TiO2, and composite oxide TiO2/SnO2 was synthesized. Nanostructured TiO2 has attracted much attention in Li insertion because it is not only a low voltage insertion host for Li, but also a fast Li insertion/extraction host. These characteristics render it a potential anode material for high-power lithium-ion batteries. The synthesized mesoporous crystalline TiO2 were tested as anode materials for their cycling ability and stability. The mesoporous TiO2 was able to reversibly accommodate Li up to Li0.5TiO2 (168 mA-hr/g) at 1-3 v vs. Li+/Li with excellent capacity retention and high rate capability on cycling. Other mesoporous crystalline metal oxide including composite TiO2/SnO2 was studied in terms of capacities and stability as anode materials. This is an abstract of a paper presented at the AIChE Annual Meeting (Salt Lake, UT 11/4-9/2007).

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Wang D, Viswanathan V, Liu J, Nie Z. Mesoporous crystalline metal oxide as anode materials for lithium ion batteries. In 2007 AIChE Annual Meeting. 2007