Mesoporous crystalline metal oxide supported Au catalysts

Donghai Wang, Zhen Ma, Sheng Dai, Jun Liu, Zimin Nie

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A novel solution growth of metal oxide nanocrystals within an organized surfactant matrix was developed into mesoporous three-dimensional nanostructured frameworks with tunable mesoporosity. Mesoporous crystalline transition metal oxides, including CeO 2 and TiO 2 , were synthesized. The new mesoporous crystalline TiO 2 or CeO 2 -supported gold nanoparticles showed high reactivity and on-stream stability towards low-temperature CO oxidation even after treatment at 400°-500°C. The gold nanoparticles were directly deposited onto the mesoporous crystalline TiO 2 or CeO 2 via deposition-precipitation methods and then subjected to heat treatment of different temperatures. The 400°C-aged Au/mesoporous metal oxide catalyst remained very active, achieving 50% conversion around -45°C, which was comparable to T50 values of as-synthesized sample. Gold supported on standard TiO 2 P25 and commercial CeO 2 prepared under the same condition and calcined at 500°C had a much higher T50 value. Stability tests showed that high temperature-aged Au/mesoporous TiO 2 or CeO 2 catalyst could maintain its activity at 28°C over an extended period of time. This is an abstract of a paper presented at the 2007 AIChE Annual Meeting (Salt Lake City, UT 11/4-9/2007).

Original languageEnglish (US)
Title of host publication2007 AIChE Annual Meeting
StatePublished - Dec 1 2007
Event2007 AIChE Annual Meeting - Salt Lake City, UT, United States
Duration: Nov 4 2007Nov 9 2007

Publication series

Name2007 AIChE Annual Meeting

Other

Other2007 AIChE Annual Meeting
CountryUnited States
CitySalt Lake City, UT
Period11/4/0711/9/07

Fingerprint

Catalyst supports
Gold
Oxides
Metals
Crystalline materials
Nanoparticles
Temperature
Metal Nanoparticles
Catalysts
Carbon Monoxide
Surface-Active Agents
Nanocrystals
Transition metals
Surface active agents
Hot Temperature
Heat treatment
Oxidation
Growth

All Science Journal Classification (ASJC) codes

  • Biotechnology
  • Chemical Engineering(all)
  • Bioengineering
  • Safety, Risk, Reliability and Quality

Cite this

Wang, D., Ma, Z., Dai, S., Liu, J., & Nie, Z. (2007). Mesoporous crystalline metal oxide supported Au catalysts. In 2007 AIChE Annual Meeting (2007 AIChE Annual Meeting).
Wang, Donghai ; Ma, Zhen ; Dai, Sheng ; Liu, Jun ; Nie, Zimin. / Mesoporous crystalline metal oxide supported Au catalysts. 2007 AIChE Annual Meeting. 2007. (2007 AIChE Annual Meeting).
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abstract = "A novel solution growth of metal oxide nanocrystals within an organized surfactant matrix was developed into mesoporous three-dimensional nanostructured frameworks with tunable mesoporosity. Mesoporous crystalline transition metal oxides, including CeO 2 and TiO 2 , were synthesized. The new mesoporous crystalline TiO 2 or CeO 2 -supported gold nanoparticles showed high reactivity and on-stream stability towards low-temperature CO oxidation even after treatment at 400°-500°C. The gold nanoparticles were directly deposited onto the mesoporous crystalline TiO 2 or CeO 2 via deposition-precipitation methods and then subjected to heat treatment of different temperatures. The 400°C-aged Au/mesoporous metal oxide catalyst remained very active, achieving 50{\%} conversion around -45°C, which was comparable to T50 values of as-synthesized sample. Gold supported on standard TiO 2 P25 and commercial CeO 2 prepared under the same condition and calcined at 500°C had a much higher T50 value. Stability tests showed that high temperature-aged Au/mesoporous TiO 2 or CeO 2 catalyst could maintain its activity at 28°C over an extended period of time. This is an abstract of a paper presented at the 2007 AIChE Annual Meeting (Salt Lake City, UT 11/4-9/2007).",
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Wang, D, Ma, Z, Dai, S, Liu, J & Nie, Z 2007, Mesoporous crystalline metal oxide supported Au catalysts. in 2007 AIChE Annual Meeting. 2007 AIChE Annual Meeting, 2007 AIChE Annual Meeting, Salt Lake City, UT, United States, 11/4/07.

Mesoporous crystalline metal oxide supported Au catalysts. / Wang, Donghai; Ma, Zhen; Dai, Sheng; Liu, Jun; Nie, Zimin.

2007 AIChE Annual Meeting. 2007. (2007 AIChE Annual Meeting).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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N2 - A novel solution growth of metal oxide nanocrystals within an organized surfactant matrix was developed into mesoporous three-dimensional nanostructured frameworks with tunable mesoporosity. Mesoporous crystalline transition metal oxides, including CeO 2 and TiO 2 , were synthesized. The new mesoporous crystalline TiO 2 or CeO 2 -supported gold nanoparticles showed high reactivity and on-stream stability towards low-temperature CO oxidation even after treatment at 400°-500°C. The gold nanoparticles were directly deposited onto the mesoporous crystalline TiO 2 or CeO 2 via deposition-precipitation methods and then subjected to heat treatment of different temperatures. The 400°C-aged Au/mesoporous metal oxide catalyst remained very active, achieving 50% conversion around -45°C, which was comparable to T50 values of as-synthesized sample. Gold supported on standard TiO 2 P25 and commercial CeO 2 prepared under the same condition and calcined at 500°C had a much higher T50 value. Stability tests showed that high temperature-aged Au/mesoporous TiO 2 or CeO 2 catalyst could maintain its activity at 28°C over an extended period of time. This is an abstract of a paper presented at the 2007 AIChE Annual Meeting (Salt Lake City, UT 11/4-9/2007).

AB - A novel solution growth of metal oxide nanocrystals within an organized surfactant matrix was developed into mesoporous three-dimensional nanostructured frameworks with tunable mesoporosity. Mesoporous crystalline transition metal oxides, including CeO 2 and TiO 2 , were synthesized. The new mesoporous crystalline TiO 2 or CeO 2 -supported gold nanoparticles showed high reactivity and on-stream stability towards low-temperature CO oxidation even after treatment at 400°-500°C. The gold nanoparticles were directly deposited onto the mesoporous crystalline TiO 2 or CeO 2 via deposition-precipitation methods and then subjected to heat treatment of different temperatures. The 400°C-aged Au/mesoporous metal oxide catalyst remained very active, achieving 50% conversion around -45°C, which was comparable to T50 values of as-synthesized sample. Gold supported on standard TiO 2 P25 and commercial CeO 2 prepared under the same condition and calcined at 500°C had a much higher T50 value. Stability tests showed that high temperature-aged Au/mesoporous TiO 2 or CeO 2 catalyst could maintain its activity at 28°C over an extended period of time. This is an abstract of a paper presented at the 2007 AIChE Annual Meeting (Salt Lake City, UT 11/4-9/2007).

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Wang D, Ma Z, Dai S, Liu J, Nie Z. Mesoporous crystalline metal oxide supported Au catalysts. In 2007 AIChE Annual Meeting. 2007. (2007 AIChE Annual Meeting).